A molecular water oxidation catalyst based on the copper complex of general formula [(Lpy)CuII]2-, 22-, (Lpy is 4-pyrenyl-1,2-phenylenebis(oxamidate) ligand) has been rationally designed and prepared to support a more extended π-conjugation through its structure in contrast with its homologue, the [(L)CuII]2- water oxidation catalyst, 12- (L is o-phenylenebis(oxamidate)). The catalytic performa...

The activity of a Te-MgO catalyst prepared by adsorbing Te vapor onto MgO powder was determined by dehydrogenation of indane, 9,10-dihydrophenanthrene, cumene, and p-cymene. The activity of the Te-MgO catalyst was higher than that of the MgO catalyst in most of the cases investigated. The selectivity of the former catalyst was much higher than that of the later in all cases studied. The Te-MgO ...

A new catalyst derived from osmium has been prepared, fully characterized and tested in the dihydroxylation of alkenes. The catalyst was prepared by wet impregnation methodology of OsCl3•3H2O on a commercial micro-magnetite surface. The catalyst allowed the reaction with one of the lowest osmium loadings for a heterogeneous catalyst and was selective for the monodihydroxylation of 1,5-dienes. M...

This review examines recent advances in photocatalytic CO2 reduction using heterogenized molecular catalysts. The main part of the discussion is focused on chemistry used to attach catalysts different supports produce hybrid materials, and how this effects performance. Examples materials for colloidal dispersions solid suspensions are presented, including those based carbon nitride, chalcogenid...

Visible-light copper photocatalysis has recently emerged as a viable technology for building sustainable synthetic processes. To broaden the applications of phosphine-ligated copper(I) complexes, we describe herein an effective metal-organic framework (MOF)-supported photocatalyst multiple iminyl radical-mediated reactions. Due to site isolation, heterogenized photosensitizer significantly high...

The promoting effect of niobium in a Li/MgO catalyst for the oxidative coupling of methane (OCM) and for the oxidattve dehydrogenation of ethane (ODHE) has been studied in some detail. it has been found that a Li/Nb/MgO catalyst with 16 wt % niobium showed the highest activity for the C, production in the OCM reaction; the activity at 600 “C was ten times that of the Li/MgO catalyst at the same...

In the present work, the transformation of m-xylene was studied over fresh and pre-coked HZSM-5 catalyst in a riser simulator over the temperature range of 350-500C.Significant differences were observed in both the activity and product selectivity pattern for the two forms of the catalyst. While, the fresh catalyst generally gave higher m-xylene conversion, the pre-coked catalyst produced highe...

A triethylaluminium(TEAl)-modified Phillips ethylene polymerisation Cr/Ti/SiO2 catalyst has been developed with two distinct active regions positioned respectively in the inner core and outer shell of the catalyst particle. DRIFTS, EPR, UV-Vis-NIR DRS, STXM, SEM-EDX and GPC-IR studies revealed that the catalyst produces simultaneously two different polymers, i.e., low molecular weight linear-ch...