Molecular dynamics simulations of the oligonucleotide duplex d(CGCGCG)2 in aqueous solution are used to investigate the glass transition phenomenon. The simulations were performed at temperatures in the 20 K to 340 K range. The mean square atomic fluctuations showed that the behavior of the oligonucleotide duplex was harmonic at low temperatures. A glass transition temperature at 223 K to 234 K...

Nuclear magnetic resonance is used to characterize local atomic motions in the glassy and supercooled liquid states of the bulk metallic glass system Pd43Ni10Cu27P20. The temperature dependence of the Knight shift reveals that certain local atomic motion decreases rapidly below a crossover temperature T(c) down to the glass transition temperature T(g). Above T(c) as well as below T(g) the mean-...

Spin-glass and chiral-glass orderings of a three-dimensional isotropic Heisenberg spin glass are studied both by equilibrium and off-equilibrium Monte Carlo simulations with emphasis on their dynamical aspects. The model is found to exhibit a finite-temperature chiral-glass transition without the conventional spin-glass order. Although chirality is an Ising-like quantity from symmetry, universa...

We study-using molecular dynamics simulations-the temperature dependence of the dynamics in a dense short-ranged attractive colloidal glass to find evidence of the kinetic glass-glass transition predicted by the ideal mode coupling theory. According to the theory, the two distinct glasses are stabilized, one by excluded volume and the other by short-ranged attractive interactions. By studying t...

The temperature dependence of the dielectric nonlinearities in a PMN single crystal and in 9/65/35 PLZT ceramics has been determined by measuring the first and third harmonic response as well as the dielectric behavior as a function of the dc electric field. In zero field a paraelectric-to-glass, and, in a high enough dc field, a glass-to-ferroelectriclike crossover in the temperature dependenc...

Glass relaxation occurs in a range of temperature during transition from equilibrium to super-cooled liquid. Viscoelastic material model can be applied to simulate glass behavior in the glass transition regime. COMSOL Multiphysics software 4.3b can simulate the stress relaxation with the WLF (WilliamsLandel-Ferry) shift function, but no structural relaxation. In this study we developed a framew...

We report the variation of glass transition temperature in supported thin films of polymer nanocomposites, consisting of polymer grafted nanoparticles embedded in a homopolymer matrix. We observe a systematic variation of the estimated glass transition temperature T(g), with the volume fraction of added polymer grafted nanoparticles. We have correlated the observed T(g) variation with the under...

the present study used a constant level of citric acid and polyvinyl alcohol and different amounts of nanocrystalline cellulose (cnc) and tio2 nanoparticles to improve the properties of starch film. the effect of different amounts of glycerol was also examined. the results of differential scanning colorimetry demonstrated that the addition of cnc increased the melting and glass transition tempe...

The logarithmic relaxation process is the slowest of all relaxation processes and is exhibited by only a few molecular liquids and proteins. Bulk salol, which is a glass-forming liquid, is known to exhibit logarithmic decay of intermediate scattering function for the β-relaxation process. In this article, we report the influence of nanoscale confinements on the logarithmic relaxation process an...

Numerical simulations of the current-voltage characteristics of an ordered two-dimensional Josephson junction array at an irrational flux quantum per plaquette are presented. The results are consistent with an scaling analysis which assumes a zero temperature vortex glass transition. The thermal correlation length exponent characterizing this transition is found to be significantly different fr...