The propagation of a reaction front through a packed bed is analyzed theoretically. The chemical reaction rate is represented by Arrhenius temperature kinetics with external transfer limitation and general power law dependency on both gaseous and solid reactant concentrations. Analogous to so-called “Activation Energy Asymptotics” developed for premixed laminar flames, the largeness of the acti...

KEY WORDS Lipase B from Candida antarctica – Kinetics – transesterification – competitive inhibition – Ping Pong Bi Bi mechanism ABSTRACT The kinetics of alcoholysis of methylpropionate and n-propanol catalyzed by Candida antarctica lipase B supported onto silanized Chromosorb P was studied in a continuous solid/gas reactor. In this system the solid phase is composed of a packed enzymatic sampl...

The kinetics of alcoholysis of methyl propionate and n-propanol catalyzed by Candida antarctica lipase B supported onto silanized Chromosorb P was studied in a continuous solid/gas reactor. In this system the solid phase is composed of a packed enzymatic sample and is percolated by nitrogen as carrier gas, which simultaneously carries substrates to the enzyme while removing reaction products. I...

Direct reduction of iron ore with H2 has become an alternative technology for production that reduces pollutant emissions. The kinetics fines in atmosphere under isothermal and non-isothermal conditions were studied by thermogravimetric analysis. X-ray diffraction scanning electron microscopy used to measure the mineral composition analyse morphology reduced fines, respectively. In experiment, ...