Pseudomonas cepacia MB2 grew on 3-chloro-2-methylbenzoate as a sole carbon source by metabolism through the meta fission pathway with the subsequent liberation of chloride. meta pyrocatechase activity in cell extracts was induced strongly by 3-chloro-2-methylbenzoate, but not by nongrowth analogs 4- or 5-chloro-2-methylbenzoate. Although rapid turnover of metabolites precluded direct identifica...

Two reactions in the catabolism of catechol by meta-fission, namely, hydration of 2-oxopent-4-enoate (vinylpyruvate) and aldol fission of the product, are catalyzed by stereospecific enzymes. The absolute configuration of this hydration product was shown to be l(S)-4-hydroxy-2-oxopentanoate. Vinylpyruvate hydratase, purified almost to homogeneity, had a molecular weight of about 287,000 and was...

Noble metal particles in the Mo-Pd-Rh-Ru-Tc system have been simulated on the atomic scale using density functional theory techniques for the first time. The composition and behaviour of the epsilon phases are consistent with high-entropy alloys (or multi-principal component alloys)—making the epsilon phase the only hexagonally close packed high-entropy alloy currently described. Configurationa...

Partitioning and transmutation (P&T) aims at making nuclear energy more sustainable from the viewpoint of the back-end of the fuel cycle by minimising the high-level waste with respect to its mass, radiotoxicity and (possibly) repository risk. P&T mainly deals with the management – i.e. transmutation and/or special conditioning and confinement – of minor actinides and fission products, but invo...

A working group composed of 30 scientists representing 12 countries and three international organisations have prepared a comprehensive status and assessment report on the Partitioning and Transmutation (P&T) of actinides and fission products in the frame work of an advanced fuel cycle option and as an alternative or complementary waste management option. The report is subdivided into two main ...