Gas-phase equilibrium adsorption of D- and L-serine (Ser) mixtures and D- and L-phenylalanine (Phe) mixtures has been studied on the naturally chiral Cu{3,1,17}(R&S) surfaces. (13)C labeling of the l enantiomers (*L-Ser and *L-Phe) has enabled mass spectrometric enantiodiscrimination of the species desorbing from the surface following equilibrium adsorption. On the Cu{3,1,17}(R&S) surfaces, bot...

In this review we discuss the fundamental role of surface forces, with a particular emphasis on the effect of the disjoining pressure, in establishing the wetting regime in the three phase systems with both plane and curved geometry. The special attention is given to the conditions of the formation of wetting/adsorption liquid films on the surface of poorly wetted substrate and the possibility ...

The strong in ̄uence of the oxide support upon the turn-over frequency (TOF) of methanol oxidation over supported metal oxide catalysts has been well documented in recent years. However, the mechanistic origins (adsorption equilibrium of methanol to methoxy species, rate-determining methoxy surface decomposition, or product desorption equilibrium) of this interesting phenomenon are not completel...

This paper investigates the bioseparation of binary protein mixtures using polystyrene based anion exchange resin. Adsorption experiments were conducted in batch mode using draft-tube internally recirculate dair lift biocontactor in comparison with the conventional shake flask batch adsorption equilibrium experiments. Binary protein mixtures contained bovine serum albumin (BSA) and bovine haemo...

11 ABSTRACT: The present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a BET surface area of 672 m2/g. The batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated carbon was 120min. The adsorption data was modeled by equilibrium and kinetic model...

introduction: boron (b) is an essential plant micronutrient whose soil availability is influenced by many soil factors.understanding the processes controling activity of boron (b) in the soil solution is important for soil fertility management. the reaction of adsorption and desorption of boron in soil determines the amount of boron that is available to plants. adsorption–desorption processes p...

Waste materials with no further treatment such as orange barks from commercial oranges may act as adsorbent for the removal of Pb. Batch kinetic and equilibrium experiments were conducted to study the effects of contact time, initial pH, adsorbent dose and initial concentration of lead. The results show that the equilibrium was achieved less than 30 min of contact time. Three adsorption isother...

The effects of the aqueous solution pH, temperature, initial solute concentration and non-equilibrium processes on the transport of acridine in saturated porous media (silica) were investigated in a series of continuous-flow column experiments. The enthalpy of the adsorption reaction was more exothermic when the solution pH was above acridine's pKa (5.6) than when it was below. The extent of ad...

Individual and competitive adsorption studies were carried out to investigate the removal of phenol and nickel ions by adsorption onto multiwalled carbon nanotubes (MWCNTs). The carbon nanotubes were characterized by different techniques such as X-ray diffraction, scanning electron microscopy, thermal analysis and Fourier transformation infrared spectroscopy. The different experimental conditio...