Surfactant-templated, mesostructured thin films are synthesized such that photoelectron donors and electron acceptors are separated spatially in the different regions of the thin film. A photoelectron donor is placed within the silica framework by using a silylated derivative of the well-known tris(bipyridine)ruthenium(II) cation. Selective placement of the electron acceptor is achieved by usin...

the main factors affecting pregnancy and implantation rates are uterine receptivity, embryo quality, and transfer efficiency. embryo transfer (et) is the last step of critically important procedure of in vitro fertilization (ivf) and probably the least successful step in assisted reproductive technology (art) treatment cascade; though simple in most of the cases, it may pose to be the most diff...

the objective of the present study is the synthesis of mwcnt-tio2 hybrid nanostructures by solvothermal synthesis method with ticl4 as precursor. the heat transfer enhancement due to the use of mwcnt-tio2 nanofluid was investigated. as-prepared hybrid materials were characterized by x-ray diffraction (xrd) and scanning electron microscopy (sem). the results showed that mwcnts were uniformly dec...

Usually the rates for electron transfer (kET) decrease with increasing donor-acceptor distance, but Marcus theory predicts a regime in which kET is expected to increase when the transfer distance gets longer. Until recently, experimental evidence for such counter-intuitive behavior had been very limited, and consequently this effect is much less well-known than the Gaussian free energy dependen...

In this review, we discuss the factors that influence electron transfer in peptides. We summarize experimental results from solution and surface studies and highlight the ongoing debate on the mechanistic aspects of this fundamental reaction. Here, we provide a balanced approach that remains unbiased and does not favor one mechanistic view over another. Support for a putative hopping mechanism ...

We studied the effect of proton-coupled electron transfer on lifetimes of the charge-separated radicals produced upon light irradiation of the thiomethyl-naphthalimide donor SMe-NI-H in the presence of nitro-cyano-pyridine acceptor (NO(2)-CN-PYR). The dynamics of electron and proton transfer were studied using femtosecond pump-probe spectroscopy in the UV/vis range. We find that the photoinduce...

Nonadiabatic processes may involve both classical-like and quantum-like coordinates. A semiclassical analysis is used to treat the contribution of the former to the Franck-Condon factor in the reaction rate expression, thereby avoiding the usual harmonic oscillator approximation. Microcanonical and canonical rate constants are calculated, yielding an expression which includes contributions from...

The effect of acceptor energy level on electron transfer rate in blends of the polymer solar-cell material poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7) is studied using time-resolved fluorescence. Fast electron transfer in less than 2 ps is observed for a driving force between 0.2 and 0.6 eV and t...

We have derived an expression for the rate of electron transfer between a semiconductor and a redox centre connected to the semiconductor via a molecular bridge. This model is particularly useful to study the charge recombination (CR) process in dye-sensitized solar cells, where the dye is often connected to the semiconductor by a conjugated bridge. This formalism, designed to be coupled with d...