A new simple and practical protocol for scalable synthesis of a novel library of propargylated and PEGylated α-hydroxy acids toward the preparation of "clickable" polylactides was described. The overall synthesis starting from readily available propargyl alcohol, bromoacetaldehyde diethyl acetal, and OEGs or PEGs was developed as a convenient procedure with low cost and no need of column chroma...

An enzyme which catalyzes the transfer of glucose from UDP-glucose to a-hydroxyisobutyronitrile (acetone cyanohydrin) has been isolated from flax seedlings (Zinum usifafissimum L). The product of this reaction was shown to be identical with linamarin, one of the two cyanogenic glucosides produced by the flax plant. The partially purified UDP-glucose-ketone cyanohydrm /3-glucosyltransferase exhi...

An enzyme which catalyzes the transfer of glucose from UDP-glucose to a-hydroxyisobutyronitrile (acetone cyanohydrin) has been isolated from flax seedlings (Zinum usifafissimum L). The product of this reaction was shown to be identical with linamarin, one of the two cyanogenic glucosides produced by the flax plant. The partially purified UDP-glucose-ketone cyanohydrm /3-glucosyltransferase exhi...

The presence of cyanide compounds restricts the utilization wild yam (Dioscorea hispida) tubers for food or ingredients. Traditional detoxification, usually used in chips processing, has not been evaluated its effectiveness reducing cyanogenic compounds. Processing into flour will increase and pregelatinization improve functional properties. This study aimed to evaluate effect 4 traditional det...

In a large number of plant species hydroxynitrile lyases catalyze the decomposition of cyanohydrins in order to generate hydrogen cyanide upon tissue damage. Hydrogen cyanide serves as a deterrent against herbivores and fungi. In vitro hydroxynitrile lyases are proficient biocatalysts for the stereospecific synthesis of cyanohydrins. Curiously, hydroxynitrile lyases from different species are c...