Nanocomposites based on TiO2-supported copper nanoparticles were prepared by a hydrothermal method where copper nanoparticles with or without the passivation of 1-decyne were chemically grown onto TiO2 nanocolloid surfaces (and hence denoted as CuHC10/TiO2 and Cu/TiO2, respectively). Transmission electron microscopy measurements showed that the size of the hybrid nanoparticles was 5-15 nm in di...

Bimetallic nanoparticles (to approximately 11 nm diameter) of CuNi and CuCo were prepared by a new synthetic route and the 1:1 atomic ratio of their constituent elements confirmed using STEM-EDS at a single particle level. These nanoparticles, supported on the native oxide layer of a silicon wafer, were studied in situ in a series of reactive gas atmospheres (H2 --> CO or CO/H2 --> O2 --> H2) u...

A novel nano-hybrid was synthesized through immobilization of amine-functionalized silica gel nanoparticles with nanomagnetite via a co-precipitation technique. The parameters, such as reagent concentrations, reaction temperature and time, were optimized to accomplish the nano-silica gel chelating matrix. The most proper amine-modified silica gel nanoparticles were immobilized with magnetic nan...

Copper(II) oxalate grown on carboxy-terminated self-assembled monolayers (SAM) using a step-by-step approach was used as precursor for the electron-induced synthesis of surface-supported copper nanoparticles. The precursor material was deposited by dipping the surfaces alternately in ethanolic solutions of copper(II) acetate and oxalic acid with intermediate thorough rinsing steps. The depositi...

A new sensitive electrochemical sensor for the detection of copper ions based on the copper ion assisted etching of Au@Ag nanoparticles was developed in this work. Since copper ions could greatly catalyze the etching process of the silver shell of Au@Ag nanoparticles in the presence of thiosulfate solutions, leading to an obvious decrease of the linear sweep voltammetry (LSV) signals of silver,...

new selective coating materials are developed and used in advanced solar collector and absorber designs with improved efficiency. cobalt and copper sulfides nanoparticles are high interest for absorbers of solar thermal collectors due to their optical properties and high absorptance in the solar wavelength range (> 96%). in the present work, cobalt and copper sulfides nanoparticles were synthes...

Copper sulfide amorphous nanoparticles and nanocrystals were prepared successfully by a special process. These CuS nanoparticles could specifically and significantly induce the apoptosis and inhibit the proliferation of human cancer cells rather than normal cells. Moreover, the biological activities of these nanoparticles are related to their polymorphs.

in this study, the biosynthesis of gold nanoparticles by penicillium chrysogenum, isolated from ahar copper mine, was investigated. the gold nanoparticles were synthesized by reducing the aqueous gold ions using the culture supernatant of the filamentous fungi. the uv–vis spectrum displayed a characteristic peak at 532 nm that is very specific for gold nanoparticles. the xrd spectrum confirmed ...

In this work, we report synthesis and characterization of copper nanoparticles in polymer matrix by wet-chemical reduction method using ascorbic acid as reducing agent, copper (II) sulfate as metal precursor and polyvinylpyrrolidone k-30 (PVP K-30) as surfactant agent. The reaction was carried out in a high-speed stirring mixture at room temperature under nitrogen atmosphere. Characterization o...

The present study has investigated the synthesis of copper nanoparticles via copper dismutation reaction in an aqueous solution and ambient conditions. Copper (II) chloride hydrate ( ), sodium oleate (SO), sodium chloride (NaCl) and ethylene diamine (EN) have been used as copper (I, II) ions source, surfactant, chloride ions supplier and ligand, respectively. Also, an amount of hydrochloric aci...