cupric oxide nanostructures were synthesized via a simple reaction between copper nitrate and sodium hydroxide using a sonochemical-assisted method. the synthesized cuo was then characterized using x-ray diffraction, scanning electron microscopy, transmission electron microscopy, fourier transform infrared, ultraviolet-visible and photoluminescence spectroscopy. our studies show that the cuo na...

A high temperature electrochemical oxidation process has been used to produce large single crystals of La 2 CuO 4+δ suitable for neutron scattering experiments. Below room temperature the oxygen-rich phases have structural superlattice scattering peaks which indicate new period-icities ranging from 2 to 6.6 layers perpendicular to the copper oxide planes. A model structure originally proposed f...

Nano-structured CuO-Cu2O complex thin film-based perovskite solar cells were fabricated on an indium tin oxide (ITO)-coated glass and studied. Copper (Cu) thin films with a purity of 99.995 % were deposited on an ITO-coated glass by magnetron reactive sputtering. To optimize the properties of the nano-structured CuO-Cu2O complex thin films, the deposited Cu thin films were thermally oxidized at...

Solar photoelectrosynthesis of methanol was driven on hybrid CuO-Cu(2)O semiconductor nanorod arrays for the first time at potentials ~800 mV below the thermodynamic threshold value and at Faradaic efficiencies up to ~95%. The CuO-Cu(2)O nanorod arrays were prepared on Cu substrates by a two-step approach consisting of the initial thermal growth of CuO nanorods followed by controlled electrodep...

Room temperature ferromagnetism (RTF) is observed in pure copper oxide (CuO) nanoparticles which were prepared by precipitation method with the post-annealing in air without any ferromagnetic dopant. X-ray photoelectron spectroscopy (XPS) result indicates that the mixture valence states of Cu1+ and Cu2+ ions exist at the surface of the particles. Vacuum annealing enhances the ferromagnetism (FM...

Well-crystallized flower-shaped copper oxide nanostructures composed of thin leaves have been synthesized by simple low-temperature chemical bath method and used to fabricate pH sensors. We examined the effect of the pH on the growth of the CuO nanostructures. By changing the pH of the precursor solution different morphologies of the CuO nanostructures were obtained. CuO nanoflowers have recent...

The nature of active copper species is well-known to vary with copper loading, i.e., isolated Cu(2+) to bulk CuO. In this work, however, the effect of copper loading on the activity and the selectivity was investigated for the wet oxidation of phenol over CuO(x)/Al(2)O(3) catalysts. The activity and the mineralization selectivity of the catalysts increased with copper loading up to 7wt% and rem...

Environmentally persistent free radicals (EPFRs) are formed by the chemisorption of substituted aromatics on metal oxide surfaces in both combustion sources and superfund sites. The current study reports the dependency of EPFR yields and their persistency on metal loading in particles (0.25, 0.5, 0.75, 1, 2, and 5% CuO/silica). The EPFRs were generated through exposure of particles to three ads...

Copper and its oxides are the main catalyst materials able to promote formation of hydrocarbons from electrocatalytic CO2 conversion. Herein, we describe a novel preparation method for carbon-doped copper oxide catalysts based on an oxidative thermal treatment copper-containing deep eutectic solvents (DES). XRD EDX analysis samples show that at 500 °C in air prolonged time (60 min) provides exc...

BACKGROUND Aryl sulfides have significant importance from biological and pharmaceutical aspects. Transition metal-catalyzed carbon-sulfur cross-coupling reaction represents an important tool for the synthesis of sulfides. Among various transition metals, copper salts or oxides have found vast applicability. RESULTS A simple procedure for the preparation of poly-ionic amberlite resins embedded...