نتایج جستجو برای: coordination reaction
تعداد نتایج: 486437 فیلتر نتایج به سال:
Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...
1- in a search directed to the reaction of compound)23(the cycloaddition reaction of 1,3- diphenylisobenzofurane)14(with p-benzoquinone)19(,followed by addition of cyclopentadiene was carried out.the specific spacial stracture of its ir,nmr,mass spectra. 2- in another attempt the kinetic stability and behavior of compounds)20(and)23(was studied.the main subject of this study was the highly reve...
A new flexible hexakis-fullerene adduct with two bis(pyridin-4-ylmethyl)malonate groups located at trans-1 positions was synthesized. Via reaction with Ag(PF6) under two different conditions, two new 1D coordination polymers were obtained; under a nitrogen atmosphere, the silver ions are connected by argentophilic interactions but under an ambient atmosphere, the silver ions exhibit no interact...
The new porous phosphine coordination material, PCM-11, is an unusual 8,4-connected coordination polymer with an open 3-D pore structure, formed by reaction of Mg(II) with tris(para-carboxylato)triphenylphosphine oxide. The highly ionic nature of the metal-ligand bonding results in excellent thermal stability upon desolvation (>460 °C). PCM-11 is easily activated for small molecule sorption at ...
Pyridyloxy cyclophosphazenes, spiro-N3P3(O2C12H8)(O-C5H4N-3)4 (L1), dispiro-N3P3(O2C12H8)2(O-C5H4N-3)2 (L2) and dispiro-N3P3(O2C12H8)2(O-C5H4N-4)2 (L3) were prepared and characterized. The crystal structure of L1 was determined which showed that the cyclophosphazene ring is planar. The reaction of L1 with anhydrous copper(II) chloride or silver nitrate afforded L2M4 metallamacrocycles [{L1}2{Cl...
The melt-phase synthesis of dioctyltin (IV) and triphenyltin (IV) benzoates were carried outusing stoichiometric amounts of benzoic acids and the corresponding organotin (IV) compounds.The reagents were ground together in a mortar and fed into a boiling glass tube. A cannula tubewas inserted into the boiling tube to discharge accumulated gaseous products. A syringe ensureda continuous flow of d...
A new high energetic copper(II) complex, [Cu(μ-DAMT)Cl2]2, was prepared in reaction between 4,5-diamino-3-methyl-4H-1,2,4-triazol-1-ium chloride (DAMT.HCl)and copper(II) nitrate and identified by elemental analysis and spectral characterization. The spectral and physical characterizations of the product confirm formation of a binuclear structure of the copper(II). In the predicted structure of ...
BACKGROUND Recent studies in anaesthesia and intensive care indicate that a team's ability to adapt its coordination activities to changing situational demands is crucial for effective teamwork and thus, safe patient care. This study addresses the relationship between adaptation of team coordination and markers of clinical performance in response to a critical event, particularly regarding whic...
Mixed-ligand Cu(II) complex was prepared by reaction of salicylaldehyde S-benzylisothiosemicarbazone hydrogenchloride ligand (H2L), Cu(ACo)2.H2O and 1,10-phenanthroline with general formulas [Cu(Phen)2Cl].H2L,Cl,H2O. Its structure was fully characterized by elemental analysis and IR method and single crystal diffraction was also used to better understanding of the molecular structure of the Cu(...
the melt-phase synthesis of dioctyltin (iv) and triphenyltin (iv) benzoates were carried outusing stoichiometric amounts of benzoic acids and the corresponding organotin (iv) compounds.the reagents were ground together in a mortar and fed into a boiling glass tube. a cannula tubewas inserted into the boiling tube to discharge accumulated gaseous products. a syringe ensureda continuous flow of d...
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