نتایج جستجو برای: co oligomerization of olefins

تعداد نتایج: 21196680  

Journal: :ChemSusChem 2012
Reiko Jennerjahn Ralf Jackstell Irene Piras Robert Franke Haijun Jiao Matthias Bauer Matthias Beller

The use of noble metal catalysts in homogeneous catalysis has been well established. Due to their price and limited availability, there is growing interest in the substitution of such precious metal complexes with readily available and bio-relevant catalysts. In particular, iron is a "rising star" in catalysis. Herein, we present a general and selective iron-catalyzed monoisomerization of olefi...

2017
Vasiliki Zacharopoulou Angeliki A. Lemonidou

Over the last decade, increasing demand for olefins and their valuable products has prompted research on novel processes and technologies for their selective production. As olefins are predominately dependent on fossil resources, their production is limited by the finite reserves and the associated economic and environmental concerns. The need for alternative routes for olefin production is imp...

Journal: :Chemical communications 2015
Renyi Shi Hua Zhang Lijun Lu Pei Gan Yuchen Sha Heng Zhang Qiang Liu Matthias Beller Aiwen Lei

A novel Pd/Cu-catalyzed chemoselective aerobic oxidative N-dealkylation/carbonylation reaction has been developed. Tertiary amines are utilized as a "reservoir" of "active" secondary amines in this transformation, which inhibits the formation of undesired by-products and the deactivation of the catalysts. This protocol allows for an efficient and straightforward construction of synthetically us...

2016
Adi E. Nako Juzo Oyamada Masayoshi Nishiura Zhaomin Hou

A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C–H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C–H bond alkylation reaction was applicable to a wide variety of tertiary amines and olefins, including functionalised styrenes and unactivated a-olefins. This work represents the...

Journal: :Chemical science 2016
Adi E Nako Juzo Oyamada Masayoshi Nishiura Zhaomin Hou

A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C-H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C-H bond alkylation reaction was applicable to a wide variety of tertiary amines and olefins, including functionalised styrenes and unactivated α-olefins. This work represents the...

Journal: :Applied Catalysis A-general 2021

The oxidative cracking of n-decane was investigated at millisecond contact times over platinum alumina washcoated monoliths a fuel-air equivalent ratio (Φ) 5. High valuable linear α-olefins were so produced through an autothermal way concomitantly with oxygenated compounds, CO, CO2, H2 and H2O. A fine identification reaction products coupled the study thermal phenomena occurring both active dea...

Journal: :Chemical communications 2006
Satoshi Minakata Yoshinobu Morino Yoji Oderaotoshi Mitsuo Komatsu

tert-Butyl hypoiodite (t-BuOI) was found to be a powerful reagent for synthesis of aziridines from olefins and sulfonamides. The aziridination of olefins was achieved by using sulfonamides with t-BuOI. Our preliminary findings represent the example of metal-free aziridination of olefins with readily accessible sulfonamides as a nitrogen source.

Journal: :journal of sciences, islamic republic of iran 2014
a. abbasi m. najafi m. masteri-farahani v. h. rodrigues

a two-dimensional nanolayered polyoxomolybdate, [4,4´-h2bipy] [mo7o22].h2o (1), where 4,4´-bipy = 4,4´-bipyridine, was prepared and characterized by ft-ir and atomic absorption spectroscopies, transmission electron microscopy (tem), x-ray single crystal and powder diffraction (xrd), and thermogravimetric analysis. the catalytic performance of 1 was assessed in the epoxidation of some olefins em...

Journal: :Angewandte Chemie 2013
Jeffrey S Cannon Robert H Grubbs

Chelated ruthenium catalysts have achieved highly chemoselective olefin metathesis reactions. Terminal and internal Z olefins were selectively reacted in the presence of internal E olefins. Products were produced in good yield and high stereoselectivity for formation of a new Z olefin. No products of metathesis with the internal E olefin were observed. Chemoselectivity for terminal olefins was ...

2017
Feilong Song Min Jia Wenwen Wei Huimin Song Yun Wu

A highly-integrated experimental system for plasma decomposition of fuels was built. Experiments were conducted and confirmed that macromolecular chain hydrocarbons were cracked by large-gap dielectric barrier discharge under the excitation of a microsecond-pulse power supply. Alkanes and olefins with a C atom number smaller than 10 as well as hydrogen were found in the cracked products of n-de...

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