Chromium pollution has been historically widespread throughout the world. Most available remediation technologies often require energy consumption. This study is aimed to develop electrochemical remediation for Cr(VI) in chromium-slag leakage with self-generated electricity. Dynamic leaching experiments of chromium-slag samples were conducted to survey the release and leaching behavior of Cr(VI...

the biosorption of hexavelent chromium from saline solutions by posidonia oceanica, a marinebiomass, was studied as a function of ph, initial chromium (vi) and salt (nacl) concentrations in batchsystem. the sorbent exhibited the maximal chromium (vi) uptake at ph 2 regardless of the presence ofincreasing salt concentration. equilibrium uptake increased with chromium (vi) concentration up to 250...

30% of the chromium ore reserves in world are concentrated Kazakhstan, during processing which large volumes wastewater containing toxic salts, formed. Сhromium is one priority components both terms emission and toxicity (for Cr(VI), maximum permissible concentration 0.05 mg/l). The compounds (III) especially (VI) have a general toxic, allergenic, carcinogenic, mutagenic effect on human body, a...

Ten years have elapsed since the International Agency for Research on Cancer (IARC) evaluated the carcinogenicity of chromium and chromium compounds. Further studies performed during the last decade have provided further epidemiological, experimental and mechanistic data which support the IARC conclusions. A wealth of results indicate that, at variance with chromium(0) and chromium(III), chromi...

Microbial enzymatic reduction of a toxic form of chromium [Cr(VI)] has been considered as an effective method for bioremediation of this metal. This study reports on the in vitro reduction of Cr(VI) using cell-free extracts from a Cr(VI) reducing Bacillus firmus KUCr1 strain. Chromium reductase was found to be constitutive and its activity was observed both in soluble cell fractions (S12 and S1...

Chromium pollution is produced in connection with industrial processes like in tanneries. It has been suggested that bioremediation could be a good option for clean up. The stress effect of variable chromate levels, pHs and growth temperatures on biochemical parameters of two Cr(VI) reducing bacterial strains Pseudomonas aeruginosa Rb-1 and Ochrobactrum intermedium Rb-2 was investigated. Transm...

Dermal exposure to sensitizing metals is a serious occupational and public health problem. The usual approach to dermal exposure assessment is to process samples by chemical methods that use reactants to digest the metal particles and quantify the mass. In the case of dermal exposure assessment, these reactants are not representative of the skin surface film liquids and hence, may overestimate ...

The extraction of chromium (VI) from hydrochloric, hydrobromic, and acetic acid solutions with Tri caprylamine oxide (TCAO) in benzene has been studied. The extractions from hydrochloric and hydrobromic, acid solutions are nearly quantitative and are partial from acetic acid solutions. The optimum conditions for extraction were established from the study of the effect of several variables like–...