OBJECTIVE The objective of this study was to clarify the influence of chromium content on surface reaction of Ti-Cr alloys in an acidic fluoride-containing saline solution. METHODS Four Ti-Cr alloys containing 5, 10, 15 or 20 mass% chromium were characterized in terms of dissolution of metals in an acidic fluoride-containing saline solution and surface structure by X-ray photoelectron spectro...

MOJ Food process Technol 2017, 4(3): 00096 The most stable oxidation states of chromium, e.g. Cr(III) and Cr(VI), exhibit significantly different biological and toxicological properties. Cr(III) is considered as an essential element for the proper functioning of living organisms, particularly in glucose metabolism, while Cr(VI) shows mutagenic effects. It is regarded as carcinogenic owing to it...

INTRODUCTION Diabetes and obesity are diseases characterized by their increasing incidence every year. When comparing with healthy subjects, the serum levels of chromium (Cr) are lowered in these two diseases. Several studies conducted in laboratory animals with experimentally- induced diabetes demonstrated that supplementation with chromium ions (III) decreased glucose concentration in the blo...

The adsorption of chromium species in soils has received much attention because of its toxicity and bioavailabilities, which are adsorption depended. There are very little studies on adsorption of chromium in sandy loam soil. Hence, this paper presents the Cr adsorption capacity of sandy loam soil under chromium spiked condition. A batch technique was used to perform cr adsorption studies. Soil...

introduction: in electroplating processes, hexavalent chromium mist is emitted in air. hexavalent chromium mist can cause lung cancer and nasal septum in workers. as permissible exposure limit (pel) of hexavalent chromium is low (0.5 µg/m 3 ) and it is used in various industries, evaluation of workers exposure to hexavalent chromium is very important. however, hexavalent chromium is relatively ...

Chromium exists primarily in two forms: trivalent and hexavalent. Trivalent chromium is present in the cationic form as Cr+3 and is an essential nutrient, but hexavalent chromium is toxic and exists as an anion, either as chromate (CrO4 -2) or dichromate (Cr2O7 -2). Therefore, the analysis of total chromium does not always provide a true indication of the effects of chromium present in a sample...

Hair and urine samples were collected from 34 male tannery workers and from 12 normal adults. Eighteen of the workers dealt directly with chromium and the remaining 16 (controls) worked in the offices and kitchen of the same factory. All were found to be clinically healthy. Chromium was determined by flameless atomic absorption spectroscopy. When compared with normal adult values, urinary chrom...

Density functional theory (DFT) has been used to investigate the conformations and thermochemistry on the singlet and triplet potential energy surfaces (PES) of Cr2(CO)10. The global minimum energy structure for the lowest singlet state of C2h symmetry is consistent with a model of two interacting Cr(CO)5 fragments in which one carbonyl in each fragment acts as an asymmetric four-electron donor...

Although in principle transition metals can form bonds with six shared electron pairs, only quadruply bonded compounds can be isolated as stable species at room temperature. Here we show that the reduction of {Cr(mu-Cl)Ar'}2 [where Ar' indicates C6H3-2,6(C6H3-2,6-Pri2)2 and Pr indicates isopropyl] with a slight excess of potassium graphite has produced a stable compound with fivefold chromium-c...

A novel radio frequency magnetron sputtering method for the deposition of composite films which consist of chromium oxide and chromium ~Cr2O3/Cr-cermet! is presented. As an extension to conventional reactive sputtering of a Cr target in an argon and oxygen atmosphere the oxygen flow into the process chamber is switched periodically on and off. This leads to an oscillating oxygen partial pressur...