Starting from the chlorogermyliumylidene chloride salt [L(Cl)Ge:]Cl (1) (L = 1,1'-methylene-3,3'-di-2,6-diisopropyl-phenylimidazole-2,2'-diylidene), the chloride ion can be easily substituted by BPh4 to yield [L(Cl)Ge:]BPh4 (3). Reaction of the latter with NaN3 furnishes [L(N3)Ge:]BPh4 (4). In contrast, the direct reaction of 1 with NaN3 affords exclusively the first azidogermyliumylidene azide...

The title compound, Ph3(PhCH2)P(+)·Cl(-)·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver di-thio-carbamate complex using benzyl-tri-phenyl-phospho-nium as the counter-ion. The asymmetric unit consists of a phospho-nium cation and a chloride anion, and a water mol-ecule of crystallization. In the crystal, the chloride ion is linked to the water mol-ecule by...

The title compound, C(9)H(12)ClN(4) (+)·Cl(-), is a natural metabolic product of imidacloprid [systematic name: (E)-1-(6-chloro-3-pyridyl-meth-yl)-N-nitro-imidazolidin-2-yl-idene-amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imidazole rings is 62.09 (12)°. The crystal structure is stabilized by N-H⋯Cl and C-H⋯Cl inter-actions...

In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N'-bidentate ligand, a water mol-ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa-hedral geometry. The Mn⋯Mn separation is 3.6563 (9) Å. In the crystal structure, O-H⋯N and O-H⋯Cl hydrogen bonds help to establish the pac...

In the title mol-ecular salt, (C10H16N2)[CoCl4], the piperazine ring of the phenyl-piperazine dication adopts a chair conformation and the phenyl ring occupies an equatorial orientation. In the tetra-chlorido-cobaltate(II) dianion, the Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the cry...

The asymmetric unit of the title salt, (C(6)H(14)N)(3)[FeCl(4)]Cl(2), consists of a tetra-hedral tetra-chloro-ferrate anion, three independent 2-methyl-piperidinium cations and two chloride ions. All the piperidine rings adopt chair conformations. In the crystal, the organic cations and the free chloride anions are linked into chains parallel to the a axis by N-H⋯Cl hydrogen bonds.

The combined activity of the 1.1.1-cryptand and of a dicopper(II) bistren cryptate complex including chloride makes the Cl(-) ion be continuously and slowly delivered to the solution, without any external intervention. The 1.1.1-cryptand slowly releases OH(-) ions, according to a defined kinetics, and each OH(-) ion displaces a Cl(-) ion from the cryptate. Chloride displacement induces a sharp ...

In the crystal structure of the title compound, C(11)H(26)N(3) (+)·Cl(-)·C(4)H(4)N(4), the (2Z)-2,3-diamino-but-2-ene-dinitrile (Z-DAMN) mol-ecules are connected with the chloride ions via N-H⋯Cl hydrogen bonds, forming ribbons running along the a axis. The guanidinium ions are located in between the ribbons formed by Z-DAMN mol-ecules and chloride ions.

The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu-Cl-Cu-N-Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N-H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl-amine cations ...

The title compound, C(6)H(8)N(3) (+)·Cl(-)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the -C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N-H⋯N hydrogen bonds, to chloride ions by N-H⋯Cl hydrogen bonds, and to water mol-ecules by N-H⋯O hydrogen bonds. Water mo...