692 nature materials | VOL 7 | SEPTEMBER 2008 | www.nature.com/naturematerials constructed chiral anionic layers based on the bridged metal centres. The synthesis involves a subtle enantioselective interaction between a solution of enantiopure cations and a racemic mixture (equal amounts of the two enantiomers) of the metallic components. The reaction leads to the formation of the desired enant...

Linear defects are generic in continuous media. In quantum systems they appear as topological line defects which are associated with a circulating persistent current. In relativistic quantum vacuum they are known as cosmic strings, in superconductors as quantized flux lines, and in superfluids and low-density atomic Bose-Einstein condensates as quantized vortex lines. We discuss unconventional ...

Optical activity and circular dichroism are fascinating physical phenomena originating from the interaction of light with chiral molecules or other nano objects lacking mirror symmetries in three-dimensional (3D) space. While chiral optical properties are weak in most of naturally occurring materials, they can be engineered and significantly enhanced in synthetic optical media known as chiral m...

Linear defects are generic in continuous media. In quantum systems they appear as topological line defects which are associated with a circulating persistent current. In relativistic quantum vacuum they are known as cosmic strings, in superconductors as quantized flux lines, and in superfluids and low-density atomic Bose-Einstein condensates as quantized vortex lines. We discuss unconventional ...

A chiral selector of cellulose-2,3-bis(3,5-dimethylphenylcarbamate) (CBDMPC) was synthesized by reacting 3,5-dimethylphenyl isocyanate with microcrystalline cellulose dissolved in an ionic liquid of 1-allyl-3-methyl-imidazolium chloride (AMIMCl). The obtained chiral selector was effectively characterized by infrared spectroscopy, elemental analysis and 1H NMR. The selector was reacted with 3-am...

experimental determination of solubility and ternary phase diagram of chiral compound are of tedious and time consuming tasks, and in many cases, there is not enough experimental data for different enantiomeric compositions to access the experimental ternary phase diagram. using thermodynamic models with predictive capability, having less dependency on experimental data, affords a great advanta...

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish between left- and right-hand circular polarization states or convert them into each other. Here we introduce an approach towards optical chirality, which is ...

Linear defects are generic in continuous media. In quantum systems they appear as topological line defects which are associated with a circulating persistent current. In relativistic quantum vacuum they are known as cosmic strings, in superconductors as quantized flux lines, and in superfluids and low-density atomic Bose-Einstein condensates as quantized vortex lines. We discuss unconventional ...