Mass action kinetics are used throughout the chemical and chemical engineering literature to describe the dynamics of systems of chemical reaction laws. They are also a special form of compartmental systems that involve mass balance relations [l]. Aside from their obvious importance in chemical engineering applications, mass action kinetics have numerous analytical properties that are of inhere...

The leaching kinetics of smithsonite ore in acetic acid solutions, an environmental friend, and natural reagent was investigated. The influence of parameters such as reaction temperature, particle size, solid-liquid ratio and acid concentration was studied in order to reveal the leaching kinetics of smithsonite ore. In this study, experimental and statistical methods were carried out in order t...

the dual fuel engines at part loads inevitably suffer from lower thermal efficiency and higher carbon monoxide and unburned fuel emission. this work is carried out to investigate combustion characteristics of a dual fuel (dieselgas) engine at part loads, using a single zone combustion model with detailed chemical kinetics for combustion of natural gas fuel. the authors developed software in whi...

In this paper, we review the construction of low-dimensional manifolds of reduced description for equations of chemical kinetics from the standpoint of the method of invariant manifold (MIM). MIM is based on a formulation of the condition of invariance as an equation, and its solution by Newton iterations. A review of existing alternative methods is extended by a thermodynamically consistent ve...

This report documents a Fortran computer code package that is used for the evaluation of gas-phase multicomponent viscosities, thermal conductivities, diiusion coeecients, and thermal diiusion coeecients. The package is in two parts. The rst is a preprocessor that computes polynomial ts to the temperature dependent parts of the pure species viscosities and binary diiusion coeecients. The coeeci...

main purpose of current study is development of a new multi zone model for direct injection diesel engines. zone configuration is based on conical shape of spray. siebers’s correlation is used for spray cone angle calculation. experimental data are used for calculation of fuel inlet mass flow rate. fuel diffusion in different zones is calculated using fick’s law. a chemical kinetics mechanism c...

The study of chemical reaction rates or “chemical kinetics” is fundamental to the study of chemistry itself and is intimately connected as well to life’s biochemical and biological processes. Most chemical reactions proceed by a complex mechanism that involves a series of elementary steps and it is often the role of chemical kinetics studies to identify these steps, with one typically expected ...