The high resolution (R=25,000) infrared M band spectrum of the massive protostar NGC 7538 : IRS9 shows a narrow absorption feature at 4.779 μm (2092.3 cm) which we attribute to the vibrational stretching mode of the CO isotope in pure CO icy grain mantles. This is the first detection of CO in icy grain mantles in the interstellar medium. The CO band is a factor of 2.3 narrower than the apolar c...

Biogas, which generated from renewable sources can be used as a sustainable energy to achieve resourceful targets of biofuel for internal combustion engines. This process can be achieved in combined absorption and adsorption chemical way. This method can be employed by aqueous solutions of calcium hydroxide, activated carbon, iron(II) chloride, silica gel and sodium sulfate respectively. The pr...

CO2 emissions from combustion flue gases have turned into a major factor in global warming. Post-combustion carbon capture (PCC) from industrial utility flue gases by reactive absorption can substantially reduce the emissions of the greenhouse gas CO2. To test a new solvent (AIT600) for this purpose, a small pilot plant was used. This paper presents the results of studies ...

Following the work of Austgen et al., the electrolyte nonrandom-two-liquid (NRTL) model was applied in a thermodynamically consistent manner to represent the vapor-liquid equilibrium (VLE) of the aqueous monoethanolamine (MEA)-CO2 system with rigorous chemical equilibrium consideration. Special attention was given to the accurate VLE description of the system at both absorbing and stripping con...

comIn the present study, CO2 removal from natural gas stream has been studied using a flat sheet membrane contactor. A three dimensional mathematical model is developed to describe the process. The model considers the transport of a gas mixture containing carbon dioxide and methane through a flat sheet membrane contactor module. The model is based on the non-wetted mode of operation, in which t...

Simple, efficient and practical CO2 capture method is reported using task-specific ionic liquid (IL) supported onto the amine-functionalized silica gel. The results have been shown that both the capacity and rate of the CO2 absorption notably increase in the supported IL/molecular sieve 4 Å system in comparison of homogeneous IL. Additionally, it has shown that the prepared material is capable ...

The improving effect of rate promoters has been investigated by experiments at pilot plant scale in conditions close to the operating conditions of the top zone of a typical hot potassium carbonate industrial packed bed absorber. The evaluation of promoter enhancement factor has been done by successive experiments with absorption of CO2 into water, into carbonate solution and into promoted carb...

Absorption process is normally used for chilled water production at district cooling plants. Besides enhancing the efficiency of the plant, the process assists in reducing the emission of CO2 to the environment. The absorption system is also installed at a district cooling plant at Universiti Teknologi Petronas. The system is operated using waste heat from the gas turbine to produce chilled wat...

This paper presents the results from using a physical absorption process to absorb gaseous CO2 mixed with N2 using water by producing tiny bubbles via a liquid-film-forming device (LFFD) that improves the solubility of CO2 in water. The influence of various parameters-pressure, initial CO2 concentration, gas-to-liquid ratios, and temperature-on the CO2 removal efficiency and its absorption rate...

Statistical mechanics and semi-empirical molecular orbital theory (PM6) are used to calculate the surface coverage of CO2 and H2 molecular species chemically adsorbed on the surface of Cu and Zn micro clusters. The calculation shows that CO2 is adsorbed well both on the surface of Cu and Zn micro clusters. Although H2 is adsorbed well on the surface of Zn micro clusters, H2 absorption on the su...