The synthesis of polynorbornene by ring opening metathesis polymerizations (ROMP) in the presence of 2 nd generation Grubbs catalyst-functionalized nanotube initiators, is reported. A full characterization of Grubbs catalyst-functionalized nanotubes was performed by FTIR (Fourier Transform Infrared Spectroscopy) and TG-DTGMS (Thermogravimetrical Analysis coupled with Mass Spectrometer), in orde...

The reaction of [Re(H)(NO)2(PR3)2] complexes (1 a: R = PCy3; 1 b: R = PiPr3) with [H(OEt2)2][BAr(F)4] ([BAr(F)4] = tetrakis{3,5-bis(trifluoromethyl)phenyl}borate) in benzene at room temperature gave the corresponding cations [Re(NO)2(PR3)2][BAr(F)4] (2 a and 2 b). The addition of phenyldiazomethane to benzene solutions of 2 a and 2 b afforded the moderately stable cationic rhenium(I)-benzyliden...

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Abstract The dataset Sustainability performance of certified and non-certified food ( https://www.doi.org/10.15454/OP51SJ ) contains 25 indicators economic, environmental, social performance, estimated for 27 value chains their conventional reference products. are at different levels the chain: farm level, processing retail level. It also raw data based on which estimated, its source, completed...

Through a modular ROMP (ring-opening metathesis polymerization) strategy, a random copolymer with anti-thrombotic activity and imaging capability has been constructed from RGD, rhodamine B and PEG modified norbornene monomers. As we expected, these tri-component polynorbornenes exhibit significant enhancement in anti-thrombotic efficacy and bioavailability in vivo.