Current industrial catalysts for the water-gas shift reaction are commonly mixtures of Fe-Cr and Zn-Al-Cu oxides, used at temperatures between 350-500oC and 180250oC, respectively. These oxide catalysts are pyrophoric and normally require lengthy and complex activation steps before usage. Improved catalysts are being sought, particularly for lower temperature (e.g., at T<150oC, equilibrium lowe...

The elevated production of reactive oxygen species (ROS) in the vascular wall is associated with cardiovascular diseases such as hypertension. This increase in oxidative stress contributes to various mechanisms of vascular dysfunction, such as decreased nitric oxide bioavailability. Therefore, anti-oxidants are being researched to decrease the high levels of ROS, which could improve the microva...

The photocatalytic performance of new TiO2/CeO2 composites is reported and the mechanism for its enhancement with respect to bare TiO2 CeO2 nanoparticles revealed. With a two- step process, shells were deposited on hollow cores forming (TiO2@H-CeO2). tuning shell deposition, optical properties engineered. absorption range was extended visible light lifetime photo-induced electron-hole pairs pro...

New information about the active sites for the water gas shift (WGS) reaction over Cu-CeO2 systems was obtained using in-situ, time-resolved X-ray diffraction (TR-XRD), X-ray absorption spectroscopy (TR-XAS, Cu K and Ce L3 edges), and infrared spectroscopy (DRIFTS). Cu-CeO2 nanoparticles prepared by a novel reversed microemulsion method (doped Ce1-xCuxO2 sample) and an impregnation method (impr...

Nowadays engineered nanomaterials (ENM) are widely used in different customer products that lead to their released into the environment. The ENM behavior in aquatic system is influenced by many factors including water chemistry, presence of natural colloids, biota etc. Despite intensive research conducted in this area the fate of ENM in aquatic system isn’t clearly understood that poses the thr...

BACKGROUND Cerium oxide nanoparticles (CeO2 NPs) are able to store and release oxygen, conferring them scavenger activity against oxidative stress. However, their effects in reproductive systems are not yet well understood. The aim of the study was to investigate the effects of exposure of refrigerated ram semen to CeO2 NPs for 96 h on the main structural and kinematic parameters of spermatozoa...

Besides cell death, nanoparticles (Nps) can induce other cellular responses such as inflammation. The potential immune response mediated by the exposure of human lymphoid cells to metal oxide Nps (moNps) was characterized using four different moNps (CeO2, TiO2, Al2O3, and ZnO) to study the three most relevant mitogen-activated protein kinase subfamilies and the nuclear factor kappa-light-chain-...

Nanosized Ag and CeO2 particles obtained through the hydrothermal method were physically mixed to obtain composite antibacterial agents. The comparative experiments of properties showed that activity nanocomposites was improved compared nanoparticles alone, which indicated synergistic effect existed between CeO2. On one hand, ICP-MS results existence suppressed silver ion release rate provided ...