Ethylbenzene (EB) dehydrogenation to styrene (SM) on an industrial scale is generally performed using classic and SMART (Styrene Monomer Advanced Reheat Technology) technologies. In the current study, spent catalysts structural changes through classic and SMART technologies were investigated and compared with the fresh catalyst. For this purpose, XRF, XRD, SEM-EDX, FT-IR, BET and crushing s...

The rate of cyclohexane photo-catalytic oxidation to cyclohexanone over anatase TiO(2) was studied at temperatures between 23 and 60 °C by in situ ATR-FTIR spectroscopy, and the kinetic parameters were estimated using a microkinetic model. At low temperatures, surface cyclohexanone formation is limited by cyclohexane adsorption due to unfavorable desorption of H(2)O, rather than previously prop...

Fluid catalytic cracking (FCC) particles account for 40 to 45% of worldwide gasoline production. The hierarchical complex particle pore structure allows access of long-chain feedstock molecules into active catalyst domains where they are cracked into smaller, more valuable hydrocarbon products (for example, gasoline). In this process, metal deposition and intrusion is a major cause for irrevers...

Ethylene polymerization by Cp2ZrCl2-B(C6F5)3-TEA catalyst system using low Al/Zr ratio has been studied with varying ethylene pressure, catalyst concentration, Al/Zr ratio, and reaction temperature. The study showed that there was an optimum condition for each variable at which maximum productivity was obtained. It was proposed that there were two competing reactions, the catalyst activation an...

Operando spectroscopic techniques (Diffusive Reflective Infrared Fourier-Transform and Mössbauer emission spectroscopy) were combined to investigate the role of oxygenates deposition on deactivation cobalt titania Fischer-Tropsch catalysts at high pressure. Clear formation carboxylates was seen for prepared via both impregnation precipitation, but more heavier impregnated catalyst. This effect ...

The in situ characterization of catalysts provides important information on the catalyst and understanding its catalytic performance selectivity for a specific reaction. Temperature programmed analyses (TPX) techniques reveal role support stabilization dispersion active sites. However, these can be altered at high temperatures since sintering species occur as well possible carbon deposition whi...

The kinetics of catalyst deactivation and coke formation during dehydrogenation of propane over supported Pt–based catalysts and, in particular, the effect of alkali metal promoters on catalyst activity and stability were studied. The analysis of propane conversion data showed that there is an optimum level of alkali metal promoter loading for both catalyst activity and stability.A model ba...

The CO2 reforming of coke oven gases (COG) was carried out over a Ni/γAl2O3 catalyst in order to obtain a suitable syngas for methanol synthesis. The influence of different operating conditions, such as temperature and volumetric hourly space velocity (VHSV), was studied. It was found that the H2 present in the feed gas promotes the Reverse Water Gas Shift reaction (RWGS), which produces water....

Inefficient use of raw materials in most catalytic processes can be attributed mainly to the deactivation of the catalyst in chemical reactors. In order to achieve efficient use of raw materials, this paper addresses mitigation of deactivation through optimization of inlet temperature-time trajectories. The optimization of temperature profiles in reactors is one of the key problems in the synth...