• Bond energies of N–N, C–C, and C–H in Na–Ga melts Ga were estimated. The atomic bondings related to C-added Na-flux GaN growth discussed. graphene with CH 4 molten First-principles molecular dynamics simulations employed for the calculations. influence above bonding states as catalysts. Bonding investigated using first-principles Activation free formation dissociation bonds estimated via blue...

In the past years, Pd0-catalyzed C(sp3)−H activation provided efficient and step-economical methods to synthesize carbo- heterocycles via direct C(sp2)−C(sp3) bond formation. We report herein that a 1,4-Pd shift allows access N-heterocycles which are difficult build reaction. It is shown o-bromo-N-methylanilines undergo at N-methyl group, followed by intramolecular trapping C(sp2)−H or another ...

In the crystal structure of the title compound, C(26)H(24)N(2)O(2), weak inter-molecular C-H⋯π inter-actions involving the benzene of the p-methoxy benzyl group and one of the phenyl rings result in the formation of chains consisting of alternating enanti-omers. Weak C-H ⋯O inter-actions with the methoxy O atom lead to the formation of layers, which are inter-linked by further C-H⋯O inter-actio...