PURPOSE The aim of this study was to evaluate microbial contamination and inhibitory effect against Streptococcus mutans (SM) of Prime & Bond (PB), Single Bond (SB) and Excite (EX) bonding systems before use, and after 10 and 20 applications. METHODS The bonding material was collected by applying a drop of the material directly on broth brain-heart infusion. The samples were homogenized, dilu...

AIM This study tested the null hypothesis that there is no difference on microleakage of dentin-bordered composite restorations using single or double coats of adhesive from one-bottle adhesive systems. METHODS AND MATERIALS The enamel surface was removed from freshly extracted bovine teeth, and standardized Class V cavities (3 x 3 x 1.5 mm) were made at the cervical areas of buccal surfaces....

PURPOSE The aim of this study was to evaluate the effect of three different adhesive systems on microleakage of Class V restorations after the use of sodium hypochlorite. MATERIALS AND METHODS One-hundred eighty bovine incisors were selected and randomly divided into 9 groups (n = 20): G1: Single Bond (SB); G2: 10% NaOCl solution (NS) + SB; G3: 10% NaOCl gel (NG) + SB; G4: Prime & Bond NT (PB...

introduction: the aim of this in vitro study was to evaluate the effect of 2% chlorhexidine (chx) on the push-out bond strength (bs) of calcium-enriched mixture (cem) cement. methods and materials: root-dentin slices from 60 single-rooted human teeth with the lumen diameter of 1.3 mm were used. the samples were randomly divided into 4 groups ( n =15), and their lumens were filled with cem cemen...

The molecular mechanisms of three intramolecular rearrangements (I, the rearrangement allyloxycycloheptatriene to yield tricyclic ketones; II, cycloaddition a nitrone-alkene render two isoxazolidines; and III, decomposition N-carbamoyl-L-proline in tetrahydro-1H-pyrrolo[1,2-c]imidazole-1,3(2H)-dione plus water, or tetrahydro-1H,3H-pyrrolo[1,2-c]oxazole-1,3-dione ammonia) have been studied by me...

This study investigated the effect of Er:YAG laser on bonding to dentin and the interaction pattern of different adhesive systems with the lased substrate. Tensile bond strength of a self-etching [Clearfil SE Bond (CSEB)] and two total-etch [Single Bond (SB) and Gluma One Bond (GOB)] systems to lased and non-lased dentin was evaluated and the adhesive interface morphology was examined by SEM. D...

The palladium-catalysed Mizoroki–Heck reaction is the most efficient route for the vinylation of aryl/vinyl halides or triflates. This reaction, in which a C C bond is formed, proceeds in the presence of a base (Scheme 1.1) [1, 2]. Nonconjugated alkenes are formed in reactions involving cyclic alkenes (Scheme 1.2) [1e, 2a,c,e,g] or in intramolecular reactions (Scheme 1.3) [2b,d–g] with creation...

The Front Cover was inspired by the painting on Sistine Chapel ceiling, made Michelangelo. Here we represent creation of new resveratrol derivatives via galvanostatic electrolysis in an undivided cell. An environmentally benign procedure developed for electrochemical oxidative mono- and bis-selenylation C(sp2)-H bond, under oxidant-, base-, transition metal-free conditions, open system at room ...

Recently a new mechanism of proton tunneling in a prism-like water hexamer was revealed [Richardson et al., Science, 2016, 351, 1310]. The tunneling motion involves the concerted breaking of two hydrogen bonds and rotations of two nearest water molecules. Eventually, this structural transformation means flipping one of the hydrogen bonds without the creation of defects in the hydrogen bond netw...