A series of tris (α-naphthyl) bismuth (V) carboxylates (α-C10H7)3Bi(OCOR)2 where OCOR = p-trifluoromethyl mandelate, pmethoxy mandelate, salicylate, 2pyrazine carboxylate, mandelate have been synthesised and characterised by solid state infrared, H and C NMR spectroscopy, molecular weight and conductance measurements. The newly synthesized derivatives are monomeric in benzene and non ionic in a...

Bismuth ferrite, BiFeO3, is the only known room-temperature magnetic ferroelectric material. We demonstrate here, using neutron scattering measurements in high quality single crystals, that the antiferromagnetic and ferroelectric order parameters are intimately coupled. Initially in a single ferroelectric state, our crystals have a canted antiferromagnetic structure describing a unique cycloid....

Bismuth oxide may be a promising battery material due to the high gravimetric (690 mAh g(-1)) and volumetric capacities (6280 mAh cm(-3)). However, this intrinsic merit has been compromised by insufficient Li-storage performance due to poor conductivity and structural integrity. Herein, we engineer a heterostructure composed of bismuth oxide (Bi2O3) and bismuth sulphide (Bi2S3) through sulfuriz...

I N T R O D U C T I O N Stabilised ~ bismuth oxide based systems form a new generation of compounds capable of improved performance in oxygen pump and oxygen sensor applications compared to the conventional stabilised zirconia based materials. The high temperature isomorph of bismuth oxide, the ~ phase, is an excellent oxygen ion conductor (I). This phase can be stabilised to room temperature b...

Quantum-confined Bi structures (quantum wells and quantum wires) are currently being studied for their varies novel properties. We now pursue the next level of quantum confinement in bismuth, quantum dots. In this work, we present a technique for the synthesis of bismuth nanoparticles using an inverse microemulsion method. To prevent air-oxidation in the characterization stage, poly(vinylpyrrol...

Saturable absorption in bismuth-doped glasses was found to have a noticeable influence on soliton interaction and group formation. This phenomenon, observed in 1450 nm mode-locked bismuth-doped fiber laser, shows the distinct feature of the multiple pulse regime, which appears as a stationary pulse group whose length can be spread over the whole cavity length by variation of the pump power and ...

In this study, the photocatalytic degradation of azo-dye acid orange 10 was investigated using titanium dioxide catalyst suspension, irradiation with ultraviolet-C lamp and bismuth vanadate under visible light of light-emitting diode lamp. Response surface methodology was successfully employed to optimize the treatment of acid orange 10 dye and assess the interactive terms of four factors. The ...

†University College London, Kathleen Lonsdale Materials Chemistry, Department of Chemistry, 20 Gordon Street, London WC1H 0AJ, UK ‡Diamond Light Source Ltd., Diamond House, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE, UK ¶Centre for Sustainable Chemical Technologies and Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK §Global E3 Institute and...

Here, a lead-free silver bismuth iodide (AgI/BiI3 ) with a crystal structure with space group R3‾ m is investigated for use in solar cells. Devices based on the silver bismuth iodide deposited from solution on top of TiO2 and the conducting polymer poly(3-hexylthiophene-2,5-diyl) (P3HT) as a hole-transport layer are prepared and the photovoltaic performance is very promising with a power conver...

This project studies the synthesis process of 2-D nanostructure of Bismuth oxycholride(BiOCl). The experiment involves synthesis of BiOCl particles and its exfoliation steps. BiOCl will be synthesized from Bismuth Nitrate (Bi(NO3)3) or Bismuth Cholride(BiCl3) with water, and Hydrochloric acid(HCl). Synthesized particles will be dispersed in Methyl Amine-Methanol solution and subjected to sonica...