Baeyer-Villiger monooxygenases (BVMOs) are biocatalysts that convert ketones to esters. Due to their high regio-, stereo- and enantioselectivity and ability to catalyse these reactions under mild conditions, they have gained interest as alternatives to chemical Baeyer-Villiger catalysts. Despite their widespread occurrence within the fungal kingdom, most of the currently characterized BVMOs are...

We introduce two generalized condensation principles: Local Club Condensation and Stationary Condensation. We show that while Strong Condensation (a generalized Condensation principle introduced by Hugh Woodin in [19]) is inconsistent with an ω1-Erdős cardinal, Stationary Condensation and Local Club Condensation (which should be thought of as weakenings of Strong Condensation) are both consiste...

Abstract δ‐Valerolactone derivatives are formed by the cerium‐catalyzed, aerobic coupling of β‐oxoesters with enol acetates and dioxygen. The products possess a 1,4‐diketone moiety, thus, conversion can be regarded as an Umpolung since oxidized to electrophilic α‐radicals. transformation has similarities Baeyer‐Villiger oxidation (BVO) where higher substituted residue migrates. An endoperoxidic...

statement of problem: when a tooth is treated endodontically, there are several objectives, which must be met for the root canal therapy to be successful. one of those objectives is the complete obturation of the root canal system. purpose: the purpose of this study was to evaluate the apical sealability of the theramfil endodontic obturation technique and compared it with lateral condensation....