the plants of the genus salvia synthesize several types of secondary metabolites with antimicrobial, cytotoxic, and radical scavenging activities and are used in the folk medicine of different countries. eleven salvia species including s. aegyptiaca, s. aethiopis, s. atropatana, s. eremophila, s. hypoleuca, s. limbata, s. nemorosa, s. santolinifolia, s. sclarea, s. syriaca, and s. xanthocheila ...

the smooth muscle of the gastrointestinal (GI) tract of dog and is potentially useful as a GI prokinetic agent. In an effort to extend the SARof the motilides, we decided to determine the effect of C-12 deoxygenation of 2 on both antibacterial and prokinetic activities. The deoxy congener with the natural (R) configuration at C-12 4 is synthetically accessible3) from erythromycin B 3, but in or...

In this paper we characterize the radical of an arbitrary‎ ‎submodule $N$ of a finitely generated free module $F$ over a‎ ‎commutatitve ring $R$ with identity‎. ‎Also we study submodules of‎ ‎$F$ which satisfy the radical formula‎. ‎Finally we derive‎ ‎necessary and sufficient conditions for $R$ to be a‎ ‎Pr$ddot{mbox{u}}$fer domain‎, ‎in terms of the radical of a‎ ‎cyclic submodule in $Rbigopl...

Let $X$ be a $BCH$-algebra and $I$ be an ideal of $X$. In this paper, we introduce the concept of $sqrt{I}$. We show that it is an ideal of $X$, when $I$ is closed ideal of $X$. Then we verify some useful properties of it. We prove that it is the ::::union:::: of all $k-$nil ideals of $I$. Moreover, if $I$ is a closed ideal of $X$, then $sqrt{I}$ is a closed translation ideal and so we can cons...

The regioselective and enantiospecific rhodium-catalyzed allylic amination of secondary allylic carbonates with N3-benzoyl thymine in conjunction with a stereoselective free radical cyclization provides a convenient method for the construction of a new conformationally rigid nucleoside.

Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient alkenes is achieved.

sec-Alkyl radicals are key reactive intermediates in the hydrocarbon combustion and atmospheric decomposition mechanisms that are formed by the abstraction of hydrogen from an alkane, or as a second generation product of n-alkyl H-migrations, C-C bond scissions in branched alkyl radicals, or the bimolecular reaction between olefins and n-alkyl radicals. Since alkanes and branched alkanes, which...

A total of 13 anthocyanins and 33 metabolites; including organic acids, phenolic acids, amino acids, organic compounds, sugar acids, sugar alcohols, and sugars, were profiled in three radish cultivars by using high-performance liquid chromatography (HPLC) and gas chromatography time-of-flight mass spectrometry (GC-TOFMS)-based metabolite profiling. Total phenolics and flavonoids and their in vi...

Calculations on the propagation steps in the radical chain oxidation of lipids (H-atom abstraction, O(2) addition) show that secondary orbital interactions play an important role in the structure and energetics of the transition states of these reactions.