نتایج جستجو برای: allylic alcohols

تعداد نتایج: 13311  

Journal: :Proceedings of the National Academy of Sciences of the United States of America 2010
Hao Jiang Nicole Holub Karl Anker Jørgensen

A simple organocatalytic one-pot protocol for the construction of optically active allylic alcohols and amines using readily available reactants and catalyst is presented. The described reaction is enabled by an enantioselective enone epoxidation/aziridination-Wharton-reaction sequence affording two highly privileged and synthetically important classes of compounds in an easy and benign way. Th...

Journal: :European Journal of Organic Chemistry 2015

Journal: :Chinese Journal of Organic Chemistry 2015

Journal: :European Journal of Organic Chemistry 2021

?-Hydroxy hydroperoxides (?-hydroperoxy alcohols) are interesting chemical platforms, notably for the preparation of 1,2,4-trioxanes, that key features numerous bioactive products such as artemisinin. In this review, main synthetic methods to prepare ?-hydroxy presented, photooxidation allylic alcohols with singlet oxygen and ring-opening epoxides H2O2. The applications also detailed, including...

Journal: :Journal of the American Chemical Society 2013
Dennis X Hu Grant M Shibuya Noah Z Burns

A new dibromination reaction involving the combination of dibromomalonate as the bromonium source and a titanium bromide species as the bromide source has been developed. Enantioselective catalysis has been achieved through apparent ligand acceleration by a tartaric acid-derived diol.

Journal: :Chemical communications 2014
Olga Soares do Rego Barros Juan Alberto Sirvent Francisco Foubelo Miguel Yus

The palladium-catalyzed allylation of N-tert-butanesulfinyl imines with allylic alcohols in the presence of InI as reducing reagent takes place with high diastereoselectivity in reasonable yields. The reaction with crotyl alcohol is totally regioselective, leading to the anti-diastereomer as the main reaction product.

2014
Chuan Wang Hisashi Yamamoto

A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant, yielding the products in 84-98% ee.

Journal: :Chemical communications 2014
Xuesong Wang Guolin Cheng Xiuling Cui

A novel and efficient approach to 3-allyl-chromones from alkynones and allylic alcohols via a tandem Michael addition-Claisen rearrangement-O-arylation reaction has been developed. Diversely structural 3-allyl-chromones were afforded in up to 93% yield for 24 examples. This synthetic strategy is regiospecific, highly efficient, environment friendly and metal-free.

Journal: :Chemical communications 2011
Takashi Ohshima Yasuhito Nakahara Junji Ipposhi Yoshiki Miyamoto Kazushi Mashima

A direct catalytic substitution of various allylic and benzylic alcohols with synthetically useful, but acid-sensitive Boc, Bus, and Dios protected amine nucleophiles, which have not been well utilized for Lewis acid catalysis, with various functionalities (OTBS, OTHP, etc.) was efficiently catalyzed by 1 mol% of Au(III) under mild conditions.

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