The synthesis of the thermally stable bicyclic diphosphasilirane O(SiiPr2P)2SiiPr2 (4) was achieved via oxidation of the alkaline earth metal substituted cyclic diphosphanide 3 with 1,2-dibromoethane. Nonetheless, during extended storage at low temperature, impurity induced rearrangement in favour of the dimeric species [O(SiiPr2P)2SiiPr2]2 (5) is observed.

Introduction Elemental beryllium is a steel gray appearing alkaline earth metal with properties like brittleness and high rigidity being the lightest among metals. The majority of beryllium is found in minerals and soils rather than in its elemental form. Beryllium is found in about 30 different mineral species like different compounds including aluminium e.g. Beryl (beryllium aluminium silicate).

A new [2+2] tetra-hydrazone macrocyclic receptor was significantly amplified in a dynamic combinatorial library upon templation with alkaline earth metal ions. After optimisation the product could be isolated in 95% yield and its interaction with ions was investigated by NMR and UV-Vis spectroscopy.

Analysis of 2-arachidonoylglycerol (2-AG) and N-arachidonoylethanolamide (anandamide) via alkali or alkaline earth metal-adduct high-energy collision-induced dissociation (CID) in fast-atom bombardment (FAB) ionization-mass spectrometry (MS) is described. The CID-MS/MS of the [2-AG+Li](+) or [2-AG+Na](+) ion undergoes charge-remote fragmentation (CRF), which is useful for the determination of t...

This highlight review overviews recent progress in fluorescence imaging technology for the alkaline-earth metal ions calcium, and magnesium, by small molecule-based fluorescent probes. Fluorescent ...

Alkaline and alkaline earth metal complexes of P,P'-diacetyl- (L1(2-)); new P,P'-dipropanoyl- (L2(2-)) and P,P'-dibenzoyl(dichloromethylene)bisphosphonates (L3(2-)) and their hydrolysis products were prepared and characterized using the single-crystal X-ray diffraction technique and spectroscopy, with the intention of studying the hydrolysis and coordinating properties of these potential prodru...

Solid-state chemistry of cluster compounds with metals in the left part of the periodic table is described. As a function of the metal valence electron concentration (VEC), characteristic changes occur with stepwise changing features. Strongly metal-metal-bonded and ligand-encapsulated clusters exist for large values of VEC. At decreased values, endohedral atoms stabilize the clusters, and with...

In the present study, an investigation on the complex formation between mono- and divalent metal ions (Na+, K+, Li+ and Mg2+) in the form of salt with different podands using various solvents has been carried out.  Isolated complexes were characterized by different spectroscopic techniques viz. IR, NMR and elemental analysis. On the basis of ...