Introduction Nopol is an unsaturated alcohol useful for the synthesis of fragrances, pesticides and household products [1]. It has been traditionally obtained by condensation of β-pinene and paraformaldehyde at high temperatures or using homogeneous Lewis acid catalysts [2]. Recently, heterogeneous catalysts: FePO4, Sn-MCM-41 and Zn-Al-MCM-41, have been reported for nopol synthesis under mild c...

MCM-41 was used as a support and, by using atomic layer deposition (ALD) in the liquid phase, a catalyst was prepared by consecutively loading titanium oxide and vanadium oxide to the support. This research analyzes the effect of the loading amount of vanadium oxide on the acidic characteristics and catalytic performance in the dehydration of butanol. The physical and chemical characteristics o...

Mesoporous silica materials (MSMs) of the MCM-41 type were rapidly synthesized by microwave heating using silica fume as silica source and evaluated as adsorbents for the removal of Cu2+, Pb2+, and Cd2+ from aqueous solutions. The effects of microwave heating times on the pore structure of the resulting MSMs were investigated as well as the effects of different acids which were employed to adju...

Pd nanoparticles were successfully introduced into the channels of mesoporous silica MCM-41 with their dispersion well-tuned. We identified the dual role played by CTAB, which was critical for both the micelle template and Pd grafting, leading to the formation of a highly active Pd-MCM-41 nanocomposite for catalysing the Suzuki reaction.

Anionic platinum carbonyl cluster has been ion paired with cinchonidium groups that are chemically bound to the surface of MCM-41 and fumed silica. In the hydrogenation of methyl pyruvate or acetophenone the fumed silica-based catalyst gives zero enantioselectivity, but under optimum conditions enantiomeric excesses of > 90 and ∼ 40%, respectively, are obtained with the MCM-41-based catalyst.

Ti-MCM-41 was synthesized at pH 3, 7 and 11. The titanium content was determined by AAS and found to be 4%, 3.2% and 4.5%, respectively. In order to increase the titanium content in Ti-MCM-41, Ti(IV) ions were grafted onto TiMCM-41 using TiCl4 in toluene and Ti(OBu)4 in ethanol. The incorporation of Ti was determined to be 28% and 30%, respectively. The oxidation of olefins such as cyclopentene...

A novel nanocomposite ZnFe(2)O(4)-TiO(2)/MCM-41 (ZTM) was synthesized by a sol-gel method and characterized through X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), N(2) adsorption-desorption, Raman spectroscopy, and ultraviolet visible (UV-vis) spectrophotometry. The results confirmed the incorporation of ZnFe(2)O(4)-TiO(2) nanoparticles inside the pores of th...