Increasing evidence indicates that silver salts can play a role in the C–H activation step of palladium-catalyzed functionalization. Here we isolate silver(I) complex by bond and demonstrate its catalytic competence for We how carbonate, common but highly insoluble additive, reacts with pentafluorobenzene presence bulky phosphine, XPhos, to form product Ag(C6F5)(XPhos). By isolating fully chara...

Imines are fundamental organic compounds used as synthetic intermediates and ligands in coordination chemistry. They also found to be important pharmacophores various bioactive compounds. In this report, two Schiff bases were prepared using the traditional condensation of 4-pyridinecarboxaldehyde with 2-thiophenemethylamine 2-quinolinecarboxaldehyde furfurylamine form (E)-1-(pyridin-4-yl)-N-(th...

The synthesis and single-crystal X-ray structure determination of the title compound [(bipy) , Pb(0 ,CMe) (O ClO )] (1) and [(bipy) Pb(ClO ) ] (2) is described. Compound (I) crystallizes in the triclinic space group P1(2), a= 7.384(2), b= 12.824(3), c= 10.622(6) A, ?= 73.41(2), ?= 80.98(2), ?= 73.68(2)', Z= 2, and R =0.033 for 3408 independent reflections .Compound (2) crystallizes in the ...

The reactions of a flexible ligand hexakis(3-pyridyloxy)cyclotriphosphazene (HPCP) with a variety of silver(I) salts (AgX; X = NO3(-), PF6(-), ClO4(-), CH3PhSO3(-), BF4(-) and CF3SO3(-)) afforded six silver(I) coordination polymers, namely {[Ag2(HPCP)]·(NO3)2·H2O}n (1), {[Ag2(HPCP)(CH3CN)]·(PF6)2}n (2), {[Ag2(HPCP)(CH3CN)]·(ClO4)2}n (3), [Ag3(HPCP)(CH3PhSO3)3]n (4), [Ag2(HPCP)(CH3CN)(BF4)2]n (5...

In recent years we have observed photoluminescence from tetrameric Cu(1) [1], Ag(I) [2], and Au(I) [ 31 clusters in solution or low-temperature glasses. In addition, emission from dimeric Au(I) complexes was reported by other groups [ 4,5 1. We assigned the luminescence of the tetramers to metalcentered s-d transitions which are modified by metal-metal interaction in these d’O clusters [ l-31. ...

The hydrothermal reaction of K(3)[Fe(CN)(6)], CuCl(2), and 2,2'-bipyridine (bipy) resulted in the formation of a 2D cyanide-bridged heterobimetallic Fe(II)-Cu(I) complex, [Fe(bipy)(2)(CN)(4)Cu(2)], 1. Working in the same conditions, but using 2,2'-bipyrimidine (bpym) instead of bipy and methanol as solvent, we obtained the homometallic Cu(I) complex [Cu(2)(CN)(2)(bpym)](2), 2. The structure of ...

Kemp’s triacid (cis,cis-1,3,5-trimethylcyclohexane-1,3,5-tricarboxylic acid, H3kta) was reacted with uranyl nitrate under solvo-hydrothermal conditions in the presence of diverse counterions or additional metal cations to give eight zero- diperiodic complexes. All coordination polymers series, [PPh3Me][UO2(kta)]·0.5H2O (1), [PPh4][UO2(kta)] (2), [C(NH2)3][UO2(kta)] (3), [Cd(bipy)3][UO2(kta)]2 (...

Multiconfigurational, intermediate valent ground states are established in several methyl-substituted bipyridine complexes of bis(pentamethylcyclopentadienyl)ytterbium, Cp2*Yb (Me(x)-bipy). In contrast to Cp2*Yb(bipy) and other substituted-bipy complexes, the nature of both the ground state and the first excited state are altered by changing the position of the methyl or dimethyl substitutions ...

OBJECTIVES The in vitro pharmacodynamics of silver(I) and silver(II) complexes of a polydiguanide ligand, chlorhexidine, were assayed to examine the value of the bactericidal endpoint as an alternative means of evaluating their antibacterial activities against burn wound pathogens. METHODS Synthesis of silver(I) chlorhexidine [Ag(I)CHX] was accomplished by in situ precipitation of the complex...