Essentially all surfaces adsorb fluids due to favourable interactions [1, 2]. For strong enough interactions, chemical bonds may be broken in the adsorbed molecules and/or established between the adsorbent and the adsorbate (chemisorption). For weak interactions, the adsorption process occurs reversibly without breaking any molecule (physisorption). Despite weak, the fluid/substrate interaction...

in this study, the batch equilibrium method was used to conduct metribuzin adsorption/desorption experiments with eight soils from different regions of iran. the results indicated that the organic carbon (oc) content, clay content, cation exchange capacity (cec), and ph had a combined effect on the metribuzin adsorption on soil. under the experimental conditions, the adsorption amount of metrib...

We have investigated the adsorption and desorption of helium near its liquid-vapor critical point in silica aerogels with porosities between 95% and 98%. We used a capacitive measurement technique which allowed us to probe the helium density inside the aerogel directly, even though the samples were surrounded by bulk helium. The aerogel’s very low thermal conductivity resulted in long equilibra...

Problems, which may arise when low-temperature nitrogen adsorption is used for the characterisation of porous materials, are discussed in this review. Continuous or discontinuous manometric techniques can be employed for nitrogen adsorption measurements at 77 K. For pore structure analysis, the nitrogen adsorption–desorption isotherms should be determined over the widest possible range of relat...

−N-succinyl-chitosan-g-polyacrylamide/attapulgite (NSC-g-PAM/APT) composite was applied as adsorbent for the removal of methylene blue (MB) from aqueous solution. The initial pH value of the dye solutions, the contact temperature, the contact time and the concentration of the dye solutions on adsorption capacity of the composite for MB dye were investigated. The adsorption kinetics and isotherm...

Two modified chitosan derivatives were prepared in order to compare their adsorption properties for Hg(II) removal from aqueous solutions. The one chitosan adsorbent (CS) is only cross-linked with glutaraldehyde, while the other (CSm), which is magnetic, is cross-linked with glutaraldehyde and functionalized with magnetic nanoparticles (Fe₃O₄). Many possible interactions between materials and H...

A novel composite matrix polymethacrylic acid-grafted Chitosan/Bentonite (PMAA-g-CS/B) was prepared through graft copolymerization reaction of methacrylic acid and chitosan in the presence of bentonite and N,N’methylene-bisacrylamide as cross linker. The composite was well characterized using FTIR, XPS, SEM, TG/DTG, surface area analyzer and potentiometric titrations. The adsorption behavior of...

The purpose of this study was to improve our understanding of the molecular organization of hydrophobic guest molecules in the presence of co-adsorbed water inside SBA-15 ordered mesoporous silica material. Understanding this adsorption competition is essential in the development of applications of controlled adsorption and desorption. The poorly water soluble drug compound itraconazole and the...

We present a comprehensive assessment of the thermophysical properties of an industrial, pilot-scale version of the prototype adsorbent, metal–organic framework 5 (MOF-5). These properties are essential ingredients in the design and modeling of MOF-5-based hydrogen adsorption systems, and may serve as a useful starting point for the development of other MOF-based systems for applications in cat...

Polyacrylonitrile (PAN)-oxime-nano Fe2O3 was used as an adsorbent for the removal of fluoride from water. The influences of contact time, initial fluoride concentration, and adsorbent dosage were investigated by batch equilibrium studies. The rate of adsorption was rapid with equilibrium being attained after 100min. The Langmuir isotherm model was found to represent the measured adsorption data...