Various radiometal complexes have been developed for tumor imaging, especially Ga-68 tracer. In the present study, the development of a radiogallium bis-thiosemicarbazone complex has been reported. [67Ga] acetylacetonate bis(thiosemicarbazone) complex ([67Ga] AATS) was prepared starting [67Ga]Gallium acetate and freshly prepared acetylacetonate bis (thiosemicarbazone) (AATS) in 30 min at 90°...

Stable green light emission and high efficiency organic devices with three polymer layers were fabricated using bis[2-(4'-tert-butylphenyl)-1-phenyl-1H-benzoimidazole-N,C²'] iridium(III) (acetylacetonate) doped in blended host materials. The 1 wt% doping concentration showed maximum luminance of 7841 cd/cm² at 25.6 V and maximum current efficiency of 9.95 cd/A at 17.2 V. The electroluminescence...

The dynamics of the early stage reaction between benzyl alcohol and Fe(acetylacetonate)3 is studied by exploiting the Dynamic Reaction Coordinate (DRC) approach, at the PBE0/6-31G* level of theory. Analysis of the DRC trajectory provides a detailed molecular insight into the catalytic effect observed in the acidic reaction environment, compared to the neutral one. The presence of an additional ...

Abstract Reaction of [Ru(acac) 2 (MeCN) ], acac − =acetylacetonate, with N ‐phenylcamphoriminoquinone (pciq) or the new ‐(2‐thiomethylphenyl)‐camphoriminoquinone (tciq) produces complexes (pciq)] and (tciq)] N,O N,S coordination E Z configuration at C=N bond, respectively. Oxidation state assignments in comparison classical iminoquinone ligands are based on structural data connection DFT calcul...