A bowl-shaped nitrogen-doped nanographene composed of a pyrrolo[3,2-b]pyrrole core substituted with six arene rings circularly bonded one another undergoes bowl-to-bowl inversion low barrier. This resembles that an umbrella flipped by the strong wind. The transition state is not planar, but possesses rather twisted, S-shaped conformation Ci symmetry. bowl-inversion mechanism follows quadruple-w...

Direct numerical simulation of a fully developed turbulent channel flow with passive scalar transport has been carried out at four Reynolds numbers, 180, 395, 640 and 1020, based on the friction velocity and the channel half width. The molecular Prandtl numbers are 0.025 and 0.71 where the working fluids are assumed to be mercury and air, respectively. It is shown that for both Prandtl numbers,...

A composite self-excited PZT-glass cantilever (4mm in length and 2mm width) was fabricated and used to measure attachment of model protein and a model pathogen. Key feature of the microcantilever is that its resonant frequency is dependent on its mass. The cantilever had a mass sensitivity of 5x10-11 g/Hz. The change in resonant frequency was measured as antibody, protein, reacts with the amine...

The photophysical properties, especially the intersystem crossing (ISC) of two heavy-atom-free BODIPY derivatives with twisted ?-conjugated frameworks (benzo[b]-fused BODIPY, BDP-B; and [a]phenanthrene-fused BDP-P), are studied steady-state time-resolved optical electron paramagnetic resonance (TREPR) spectroscopic methods as well ADC(2) theoretical investigations. Interestingly, BDP-B has a pl...

This paper presents an enhanced seeding rule for the design and fabrication of line seeds glancing angle deposition (GLAD). GLAD is capable creating nanometer-level three-dimensional (3D) features by ballistic shadowing from natural/artificial nuclei at oblique incident angles in physical vapor processes. The features, including columns, springs, zigzags, ribbons, are building blocks a wide ran...

introduction: effect of tripolar tens of vertebral column on slow and fast motoneurons (mns) activity of soleus muscle was previously investigated. in this study for better differentiation of the behavior of slow and fast mns, we exploited h-reflex recovery curve recording in two muscles of soleus and lateral gastrocnemius, respectively as the representatives of slow and fast muscles. methods: ...

This controlled study compared the strength and porosity of 48 polymethylmethacrylate cement-implant constructs prepared with open bowl versus vacuum mix technique. Forty-eight blast finished stainless steel rods of 13 mm diameter were implanted with centralizers into 17-mm inner diameter tubes that had been retrograde filled with polymethylmethacrylate cement. The eight cement preparations use...

A novel large self-expanding endovascular stent was designed with strut thickness of 70 μm × 70 μm width. The method was developed and investigated to identify a novel simpler technique in aortic aneurysm therapy. Stage 1 analysis was performed after deploying it in a virtual aneurysm model of 6 cm wide × 6 cm long fusiform hyper-elastic anisotropic design. At cell width of 9 mm, there was no b...