Abstract Princivalleite, Na(Mn 2 Al)Al 6 (Si O 18 )(BO 3 ) (OH) O, is a new mineral (IMA2020-056) of the tourmaline supergroup. It occurs in Veddasca Valley, Luino area, Varese, Lombardy, Italy (46°03’30.74’’N, 8°48’24.47’’E) at centre narrow (2–3 cm wide) vertical pegmatitic vein, few metres long, crosscutting lens flaser gneiss. Crystals are subhedral (up to 10 mm size), azure with vitreous l...