A study has been presented on the effects of intrinsic mechanical parameters, such as surface stress, surface elastic modulus, surface porosity, permeability and grain size on the corrosion failure of nanocomposite coatings. A set of mechano-electrochemical equations was developed by combining the popular Butler-Volmer and Duhem expressions to analyze the direct influence of mechanical paramete...

The synthesis, characterization and the biological study of a series of Ni(ll)(2)(carboxylato)(2) [12- MC(Ni(II)N(shi)2(pko)2)-4][12-MC(Ni(ii)N(sh03(pko))-4] (CH(3)OH)(3)(H(3)O) fused 12-membered metallacrowns with 10 metal ions and commercial available herbicides or anti-inflammatory drugs as carboxylato ligands are reported. All the compounds have a mixed ligand composition with salicylhydrox...

Ni-based superalloys are the important materials for gas turbines in advanced aeroplane engines . The addition of refractory elements to these superalloys, such as rhenium and tungsten, can significantly improve the hightemperature performance by so-called solid-solution hardening. Although the strengthening effect of refractory elements in Ni-based superalloys have been known for a long time, ...

The three-coordinate Ni(I) complex Ni(Cl)(P(2)), where P(2) is the diphosphine (iPr)DPDBFphos, reacts with the acids HCl·(dioxane) and 2,6-lutidinium chloride to generate Ni(H)(Cl)(P(2)) and Ni(Cl)(2)(P(2)). Photolysis of the Ni(H)(X)(P(2)) (for X = Cl, Br) results in formation of H(2) and the Ni(I) halide. This reaction also proceeds in reverse when heated.

Nickel hyperaccumulator plants contain unusually elevated levels of Ni (> 1 000 μg Ni/g). Some insect herbivores, including Lygus hesperus (Western tarnished plant bug), have been observed feeding on the California Ni hyperaccumulator Streptanthus polygaloides. This bug may be able to utilize S. polygaloides as a host either through its feeding behavior or by physiological tolerance of Ni. This...

The adsorption, dissociation, and diffusion of hydrogen in Ni(100) and Ni(100)/YSZ(100) slabs with two different interfaces (Ni/cation and Ni/O interface) have been studied by the density functional theory (DFT) with the Perdew-Wang functional. The H(2) molecule is found to preferentially absorb on a Top (T) site with side-on configuration on the Ni(100) surface, while the H-atom is strongly bo...

The coupling effect of interfacial reactions between two pads in Ni-SnAg-Cu and Au/Ni/Cu-SnAg-Cu solder joints was investigated in this paper. After reflow soldering, a large amount of Cu can diffuse across the solder joint to the opposite pad to form (Cu,Ni)6Sn5 IMC on the Ni pad in Ni-SnAg-Cu solder joint. A little Ni can also be detected in Cu6Sn5 layer, which contains some trapped solder, o...

Excessive accumulation of nickel (Ni) can be toxic to plants. In Arabidopsis thaliana, the Fe²⁺ transporter, iron (Fe)-regulated transporter1 (IRT1), mediates Fe uptake and also implicates in Ni²⁺ uptake at roots; however, the underlying mechanism of Ni²⁺ uptake and accumulation remains unelucidated. In the present study, we found that zinc (Zn) deficient conditions resulted in increased accumu...

was also isolated and structurally characterized. In the absence of alkaline cations during the synthesis, a mixed salt associating [Ni(S2O4)2] 1 with Ni was isolated, and formulated as (Ni,H2O)[Ni(S2O4)2]2, with the Ni 2+ cation weakly bonded to two crown ether moieties. The salt exhibits an unprecedented solid state association with extremely short S S intermolecular contacts [3.332(2) Å], le...