The characteristics of enzymatic/mild acidolysis lignin (EMAL) isolated from moso bamboo were investigated using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Pyrolysis temperature as a factor on products was studied, and the pyrolysis mechanism was inferred with respect to the dominating products. Research results showed that pyrolysis products derived from EMAL pyrolysis were mai...

We estimate the profitability of producing biochar from crop residue (corn stover) for two scenarios. The first employs slow pyrolysis to generate biochar and pyrolysis gas and has the advantage of high yields of char (as much as 40 wt-%) but the disadvantage of producing a relatively low-value energy product (pyrolysis gas of modest heating value). The second scenario employs fast pyrolysis to...

The pyrolysis of TVSb has been investigated in a flow tube reactor using Dz and He carrier gases. For TVSb alone, the most likely pyrolysis reaction involves an Sbcentered reductive elimination pathway. A less likely possibility is pyrolysis via homolysis of the Sb-C bonds, yielding vinyl radicals. Unfortunately, examination of the organic byproducts in both He and D, yields insufficient inform...

The paper introducedeffects of modified pyrolysis tar on flue gas desulfurization. This experiment selected the pyrolysis tar as the raw material, researched the effects on desulfurization performance under different modification solution, concentration, solid liquid ratio of pyrolysis tar and modified solution, calcination temperature and calcination time by 16 group orth...

Analytical pyrolysis is a technique currently used for investigating structural features of complex macromolecular materials. However, pitfalls appear to be widespread in pyrolysis studies of humic substances, and serious limitations can be experienced during the analytical procedure due to thermal reactions and configuration of the pyrolysis units and chromatographic systems. Pyrolysis present...

The present work deals with an experimental investigation into the generation and characterization of pyrolytic oil biochar from Sal wood sawdust (SW). pyrolysis experiment was performed in a semi-batch reactor at 500 oC 80 oC/min heating rate CaO, CuO, Al2O3 catalysts. Further, were investigated using different analyses, including proximate analysis, elemental thermal stability, GC-MS, FTIR, f...

The slow pyrolysis characteristics of lignocellulosic biomass and its three major components via a Thermogravimetric Analyzer coupled with Fourier Transform Infrared Spectrometer (TGA-FTIR) was studied. Different compositions ratios cellulose, hemicellulose, lignin, olive pomace, sunflower waste, pinecone were selected. main decomposition temperature ranges xylose (hemicellulose) lignin showed ...

This thesis consists of uncertainty and techno-economic studies of two different biofuels production pathways (catalytic pyrolysis and gasification). The objective of this paper is to obtain a side-by-side techno-economic comparison of in situ and ex situ catalytic pyrolysis, and gasification state-of-technology and target scenarios that addresses both sensitivity and uncertainty analysis in th...