محمد رضا یافتیان
استاد گروه شیمی ، دانشکده علوم، دانشگاه زنجان، زنجان، ایران
[ 1 ] - مطالعه کارائی زیست فیلتر ستونی چای کمپوست برای حذف برخی یون‌های فلزی سنگین از محلول‌های آبی
در مطالعه حاضر، یک بیوفیلتر جدید با استفاده از چای کمپوست تهیه و در مطالعه حذف یون‌هایCo2+ ،Cu2+ ،Pb2+ و Ni2+ بهکار برده شد. در این تحقیق تاثیر عامل pH در محدوده 2 تا 6 بر روی فرآیند حذف فلزها نشان داد که بهترین pH برای حذف این یون‌ها برابر 5 pH=می‌باشد. تاثیر زمان و مقدار جذب شده در روی فرآیند حذف مطالعه شد و نتایج نشان داد که با افزایش زمان تماس و مقدار جاذب، درصد حذف افزایش می‌یابد. بر...
[ 2 ] - Selective and Efficient Solvent Extraction of Copper(II) Ions from Chloride Solutions by Oxime Extractants
Oxime extractants 3-tert-butyl-2-hydroxy-5-methyl benzaldehyde oxime (HL1) and 3-tert-butyl-2-hydroxy-5-methoxy benzaldehyde oxime (HL2) were synthesized and characterized by conventional spectroscopic methods. Suitable lipophilic nature of the prepared extractants allowed examining the ability of these molecules for extr...
[ 3 ] - Selective Liquid-Liquid Extraction of Lead Ions Using Newly Synthesized Extractant 2-(Dibutylcarbamoyl)benzoic Acid
A new carboxylic acid extractant, named 2-(dibutylcarbamoyl)benzoic acid, is prepared and its potential for selective solvent extraction and recovery of lead ions from industrial samples was investigated. The slope analysis indicated that the lead ions are extracted by formation of 1:2 metal to ligand complexes. The effect of the parameters influencing the extraction efficiency including kind o...
[ 4 ] - Effect of Polyethylene Glycols Dissolved in Aqueous Phase on the Extraction-Separation of La(III), Eu(III) and Er(III) Ions with Bis(2-ethylhexyl)phosphoric Acid
The present work concerns on the investigation of the role of polyethylene glycols (PEGs) as masking agent for amelioration of extraction-separation of La(III), Eu(III) and Er(III) ions by the acidic extractant bis(2-ethylhexyl)phosphoric acid (DEHPA). The studied solvent extraction system is based on the combination of chelating effect of DEHPA in the organic phase on the one hand, and the bin...
[ 5 ] - Th(IV)/U(VI) Sorption on Modified SBA–15 Mesoporous Materials in Fixed–Bed Column
The sorption of thorium and uranium ions by functionalized SBA–15 mesoporous silica materials with Schiff base ligating groups N–propylsalicylaldimine (SBA/SA) and ethylenediaminepropylesalicylaldimine (SBA/EnSA) from aqueous solution was investigated in fixed-bed column method. The TEMPeffect of pH, sample solution volume, and the column design parameters such as sample and eluent flow rat...
[ 6 ] - Selective and Efficient Ligandless Water-in-Oil Emulsion Liquid Membrane Transport of Thorium(IV) Ions
The present paper concerns on the selective and very efficient transport of thorium(IV) ions from aqueous solutions through an emulsion liquid membranes composed by paraffin and a surfactant, without carrier requirement. The influence of pH of the external aqueous phase, the surfactant concentration in the membrane phase, the type, and concentration of th...
[ 7 ] - Extraction-Separation of Eu(III)/Th(IV) Ions with a Phosphorylated Ligand in an Ionic Liquid
Extraction-separation of Eu(III) and Th(IV) ions from nitrate media into the ionic liquid 1-hexyl-3-methylimidazolium hexafluorophosphate by a phosphorylated salen extractant, bis(chlorophosphoryle)decahydro-2,4-di(2-hydroxyphenyl)benzo[d][1,3,6]oxadiazepine (DPO), is investigated. It is found that Eu(III) ions are extracted via a solvation mechanism, and the extraction of Th(IV) i...
[ 8 ] - A Study on the Extraction of Cd(II), Co(II) and Ni(II) Ions by Bis(2-ethylhexyl)phosphoric Acid and 2-Thenoyltrifluoroacetone
Keep in mind the importance of cadmium, cobalt and nickel ions as environmentally and economically strategic heavy metals, the application of two acidic extractants, named bis(2-diethylhexyl)phosphoric acid (DEHPA) and 2-thenoyltrifluoroacetone (HTTA), was assessed for the extraction-recovery of these ions from leached solution of spent rechargeable Ni-Cd batteries. The conditions for leach...
[ 9 ] - Mobile Carrier Properties of N2O2- and N3O2-Type Schiff Base Molecules Towards Copper(II) Ions
Mobile carrier properties of two schiff base ligands, named <span style="font-size: 10.0pt; font-family: 'Times New Roman','serif'; mso-fareast-font-family: 'Times New Roman'; mso-ansi-langua...
[ 10 ] - Extractive Properties of Tri-n-octylphosphine Oxide Towards Thorium (IV) and Europium (III) Ions in Aqueous Nitrate Media
Phosphoryl containing ligand tri-n-octylphosphine oxide (TOPO) in dichloromethane has been used as an extracting agent for tetravalent thorium and trivalent europium ions from their 1 M sodium nitrates. The equilibrium data reveal that both ions are extracted as the complexes at 1:3 metal/ligand ratio. The values of conditional extraction equilibrium constant (Kex) show the superior extract...
[ 11 ] - Wastewater Treatment by Using Polyurethane Foams Modified with Bis-[2-ethylhexyl] Phosphoric Acid: Kinetics, Equilibrium and Desorption Studies
Background: Water pollution is an important environmental problem, undoubtedly, the presence of toxic heavy metals forms the main source of water contamination. Sorption characteristics of polyurethane foams modified with bis (2-ethylhexyl)phosphoric acid (DEHPA) for the removal of zinc, lead and cadmium ions from contaminated solutions were investigated. Methods: Operating variables, such as ...
[ 12 ] - بررسی پراکنش فلزهای سنگین در خاکهای اطراف کارخانه سرب و روی زنجان
آلودگی خاک به فلزهای سنگین یک مشکل اساسی و در حال گسترش در کشور ما به شمار میآید. بنابراین آگاهی از الگوی توزیع مکانی خاکهای حاوی فلزهای سنگین، میتواند نقش مهمی در ارزیابی پتانسیل آلودگی در یک منطقه داشته باشد. با این هدف در این پژوهش تلاش شدتا با استفاده از علم آمار مکانی، الگوی مکانی حاکم و تغییرات مکانی برخی از فلزهای سنگین شامل کبالت، نیکل، مس، روی، کادمیومو سرب در خاکهای اطراف کارخانه ...
[ 13 ] - The Role of Polyethylene Glycols Dissolved in Aqueous Phase on the Extraction-Separation of Zn(II) and Pb(II) by Bis(2-ethylhexyl)phosphoric Acid
The presented study describes the solvent extraction process of Zn(II) and Pb(II) from aqueous solutions by a cation exchanger extractant named bis(2-ethylhexyl)phosphoric acid (DEHPA). The results confirm that both of the extraction efficiency and extraction selectivity depend on the employed organic diluent. The applied extractant was selective towards zinc ions; this selectivity did not depe...
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