Ming Lu
College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China
[ 1 ] - A novel and efficient procedure for the preparation of benzyl alcohol by hydrolysis of benzyl chloride catalyzed by PEG1000-DAIL[BF4]/Fe2(SO4)3 under homogeneous catalysis in aqueous media
In this work, benzyl alcohol was obtained in 96% excellent yield by hydrolysis of benzyl chloride catalyzedby the recyclable temperature-dependant phase-separation system that comprised the ionic liquid PEG1000-DAIL[BF4], toluene and ferric sulfate under homogeneous catalysis in aqueous media. This novel methodnot only enhanced the yield, but also made the operating units easy workup. The catal...
[ 2 ] - A novel mathematical model of formulation design of emulsion explosive
A novel mathematical model has been developed to aid the formulation of emulsion explosives. This mathematical model calculated heat of explosion, oxygen balance and raw material cost as a function of explosive ingredients, and the solution of the mathematical model was obtained by a MS Excel program. The effects of the different content of NH4NO3, NaNO3, H2O, and span-80 and composite fuel oil...
[ 3 ] - Potassium carbonate as a base for cycloalkylation of diethyl malonate and ethyl cyanoacetate in solid-liquid two phase systems
The cycloalkylation of diethyl malonate and ethyl cyanoacetate with alkyl dihalide was investigated by using comminuted potassium carbonate as a base and toluene as a solvent in the presence of hexadecyltrimethylammonium bromide (HTMAB) as a phase-transfer catalyst, which provided a conventional procedure with the advantage of short reaction period and high product yield. The factors influencin...
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