Mohsen Najafi
Qom University of Technology, P. O. Box 1519-37195, Qom, Iran
[ 1 ] - Mathematical modeling the effect of catalyst initial shape and the crack pattern in olefin copolymerization
A two-dimensional (2D) single particle model for the copolymerization of propylene-ethylene with heterogeneous Ziegler-Natta catalyst is developed. The model accounts for the effects of the initial shape of the catalyst and carck/ pore patterns on the copolymer composition, polymerization rate and the average molecular weight properties. The spherical and oblate ellipsoidal shapes of catalyst p...
[ 2 ] - Modelling the catalyst fragmentation pattern in relation to molecular properties and particle overheating in olefin polymerization
A two-dimensional single particle finite element model was used to examine the effects of particle fragmental pattern on the average molecular weights, polymerization rate and particle overheating in heterogeneous Ziegler-Natta olefin polymerization. A two-site catalyst kinetic mechanism was employed together with a dynamic two-dimensional molecular species in diffusion-reaction equation. The i...
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