Ghodsi Mohammadi Ziarani
Department of Chemistry, Alzahra University, Vanak Square, Tehran, Iran, P.O. Box 1993893973.
[ 1 ] - Synthesis of the biologically active henna based benzochromene derivatives using ionic liquid functionalized SBA-15 as a nanoreactor
SBA-15 was prepared and then functionalized with N-methyl-N’-propyltrimethoxysilyl imidazolium chloride as ionic liquid moiety. The ionic liquid functionalized SBA-15 (SBA-IL) was characterized by different analytical techniques including FT-IR, N2 adsorption-desorption, TGA and SEM image. According to the obtained results it was found that the organic groups were g...
[ 2 ] - Preparation and characterization of ionic liquid functionalized SBA-15 and its application in the synthesis of 2,3-dihydroquinazolinones
N-Methyl-Nʹ-propyltrimethoxysillylimidazolium chloride was prepared as ionic liquid (IL) containing silylating agent and then used for modification of the internal surface of SBA-15 to gain a heterogeneous ionic liquid catalyst. Subsequently, the obtained SBA-IL was characterized using various techniques, including SEM and TEM images, FT-IR, X-ray diffraction, TGA/DTA and BET ...
[ 3 ] - One-pot synthesis of tetrahydropyrimido[4,5-b]quinoline derivatives using sulfonic acid functionalized SBA-15 and their antimicrobial activities
A Simple and efficient method for synthesis of tetrahydropyrimido[4,5-b]quinoline derivatives via three component reaction of aromatic aldehydes, dimedone and 6-amino uracil derivatives using a catalytic amount of sulfonic acid functionalized nanoporous silica (SBA-15-Pr-SO3H) is described. The advantages of this method are easy and clean work-up, high yield, mild reaction c...
[ 4 ] - Fast one-pot synthesis of 1,8-dioxo-decahydroacridine derivatives using sulfonic acid functionalized LUS-1 and the study on their antimicrobial activities
Mesoporous silica LUS-1 (Laval University Silica) was successfully functionalized by propyl sulfonic acid and was used as a recyclable catalyst for the synthesis of acridine-1,8-diones via a pseudo four component reaction of aromatic aldehydes, dimedone and ammonium acetate (or anilines). The excellent yields, short reaction time, simple work-up procedure, and environmentally friendly condition...
[ 5 ] - Application of SBA-Pr-SO3H as a solid acid nanoreactor in the Biginelli reaction
Sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) with a pore size of 6 nm catalyzed three component coupling of aromatic aldehydes, urea and ethyl acetoacetate to afford the corresponding dihydropyrimidinones under solvent free condition. This new protocol for Biginelli reaction has important advantages such as green synthesis, short reaction time, easy isolation and high yields of ...
[ 6 ] - Green synthesis of bis(indolyl)methanes in water using sulfonic acid functionalized silica (SiO2-Pr-SO3H)
Bis(indolyl)methanes are important group of bioactive metabolites of terrestrial and marine regions. They were synthesized by different methods. Herein, a clean, one-pot synthesis of bis(indolyl)methane derivatives by cyclo-condensation reaction of indole and various aldehydes using Sulfonic acid functionalized silica (SiO2-Pr-SO3H) in aqueous media is reported. The advantages of this new metho...
[ 7 ] - Green Synthesis of Pyrazol‑chromeno[2,3‑d]pyrimidinones Using SBA-Pr-SO3H as an Efficient Nanocatalyst
Hexagonal mesoporous silica (SBA-15) was prepared and then functionalized by(3-mercaptopropyl)trimethoxysilane. The obtained 3-mercaptopropyl functionalized SBA-15 (SBA-Pr-SH) was then oxidized using H2O2 in methanol under an acidic condition to give sulfonic acid functionalized mesoporous silica (SBA-Pr-SO3H). Th...
[ 8 ] - Amino Ethyl-Functionalized SBA-15: A Promising Adsorbent for Anionic and Cationic Dyes Removal
Batch Adsorption of Acid Red 37 (AR37) and Basic Orange 2 (BO2) on amino ethyl-functionalized SBA-15 have been studied. SBA-15 was synthesized and functionalized according to the procedure in the literature. Amino ethyl-functionalized SBA-15 showed the BET surface area 520 m2/g and pore diameter 7.02 nm, based on adsorption-desorption of N2. SEM image shows lengthy fib...
[ 9 ] - An Efficient Green Approach for the Synthesis of Structurally Diversified Spirooxindoles Using Sulfonic Acid Functionalized Nanoporous Silica (SBA-Pr-SO3H)
One-pot multicomponent reaction between isatin, barbituric acid, and 6-amino-1,3-dimethyl uracil was investigated <span style="font-size: 10.0pt; ...
[ 10 ] - Application of Sulfonic Acid Functionalized Nanoporous Silica (SBA-Pr-SO3H) in the Green One-pot Synthesis of Polyhydroacridine Libraries
1,8-Dioxo-decahydroacridines have been synthesized by the three-component reaction of aromatic aldehydes, aromatic amines (or ammonium acetate), and dimedone in the presence of sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) under solvent-free conditions. Excellent yields, short reaction times, mild reaction conditions, an...
[ 11 ] - Synthesis of 3,4-Dihydropyrano[c]Chromene Derivatives Using Sulfonic Acid Functionalized Silica (SiO2PrSO3H)
3,4-ِDihydropyrano[c]chromene derivatives were synthesized using sulfonic acid functionalized silica (SiO2-Pr-SO3H) as a highly efficient heterogenous solid acid catalyst via one-pot three-component condensation of aromatic aldehydes with malononitrile and 4-hydroxycoumarin in excellent yields.
[ 12 ] - One Pot Synthesis of Polyhydroquinolines Catalyzed by Sulfonic Acid Functionalized SBA-15 as a New Nanoporous Acid Catalyst under Solvent Free Conditions
Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H) as a new nanoporous acid catalyst was used in the one-pot synthesis of polyhydroquinolines derivatives via the Hantzsch four component condensation reaction of aldehydes, b-ketoesters, dimedone and ammonium acetate under solvent free conditions with short reaction time in excellent yields. SBA-P...
[ 13 ] - A Short Method for the Synthesis of Alpha-Tocopherol Side Chain
The enzymatic hydrolysis of meso-1,7-diacetoxy-2,6-dimethylheptane 5, prepared from 2,6-dimethylhepta-1,6-diene 6, gave the (2S,6R)-7-acetoxy-2,6-dimethyl-1-heptanol 1, which was transformed to the (2R,6R)-2,6,10-trimethyl-1-undecanol 7. In this manner, the C14 side chain of a-Tocopherol was synthesized from 2,6-dimethylhepta-1,6-diene 6 in only 5 steps.
[ 14 ] - Efficient Synthesis and Antimicrobial Evaluation of Pyrazolopyranopyrimidines in the Presence of SBA-Pr-SO3H as a Nanoporous Acid Catalyst
A simple, efficient, and environmentally friendly method has been developed for the synthesis of a series of tricyclic fused pyrazolopyranopyrimidines via a one-pot three-component reaction of barbituric acids, aromatic aldehydes, and 3-methyl-5-pyrazolone in the presence of SBA-Pr-SO3H. SBA-15 mesoporous silica material functionalized with propyl sulfonic acid groups was used as a heterogeneou...
[ 15 ] - Synthesis of Some Spiro Indeno[1,2-b]pyrido[2,3-d]Pyrimidine-5,3′- Indolines as New Urease Inhibitors
New series of spiroindeno[1,2-b]pyrido[2,3-d]pyrimidine-5,3′-indolines as new urease inhibitors were synthesized by the catalytic procedure in high yield and short reaction time. In this method, biacidic carbon was prepared as a novel heterogeneous acid and was subsequently used as an efficient catalyst in this synthesis. The inhibitory activities of synthesized compounds were tested against Ja...
[ 16 ] - Green Synthesis and Urease Inhibitory Activity of Spiro-pyrimidinethiones/spiro-Pyrimidinones-barbituric Acid Derivatives
Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H) with pore size 6 nm as an efficient heterogeneous nanoporous solid acid catalyst exhibited good catalytic activity in the Biginelli-like reaction in the synthesis of spiroheterobicyclic rings with good yield and good recyclability. Spiro-pyrimidinethiones/spiro-pyrimidinones-barbituric acid derivatives were synthesized in a simple and efficient ...
[ 17 ] - A Novel Approach for Preparation of Acetylacetonate Complex Anchored to High Order Nanoporous Silica (LUS-1)
Tris(3-bromo-acetylacetonato) chromium(III) as an inert and very stable complex with a good leaving group was synthesized using as-prepared Cr(acetylacetonate)3. Highly ordered nanoporous silica (LUS-1), with some great features, was functionalized with 3-aminopropyltriethoxysilane. Then the as-prepared product was modified with tris(3-bromo-acetylacetonato) chromium(III) under mild reaction co...
[ 18 ] - Application of Sulfonic Acid Functionalized SBA-15 as a Nanoporous Acid Catalyst in Microwave Assisted Synthesis of 2-Aryl Benzoxazoles
Sulfonic acid functionalized SBA-15 as a nanoporous acid catalyst was used in the synthesis of 2-Aryl benzoxazoles 4 by the condensation of 2-aminophenol 1 and benzoyl chlorides 2 under microwave irradiation in solvent free reaction conditions. The advantages of this methodology are good product yields (60-98%), being environmentally benign, short reaction times and easy work up.
[ 19 ] - Ethylenediamine Functionalized Nanoporous Silica Type LUS-1 for Highly Sensitive Analysis of Pb2+ , Cd2+ and Zn2+ in Various Samples
In this work, a novel method is described for the preconcentration of Pb2+, Cd2+ and Zn2+ ions in environmental samples using uniform silanized mesopor (LUS-1) functionalized by ethylenediamine groups as a new extractant. The determination of ions is done by inductively coupled plasma optical emission spectrometry (ICP-OES). The extraction time and efficiency, p...
[ 20 ] - Convenient One-Pot Synthesis of Spirooxindole-4H-pyrans in the Presence of SBA-Pr-NH2 and Evaluation of their Urease Inhibitory Activities
A simple and efficient one-pot three-component synthesis of the biologically important spirooxindole-4H-pyrans was carried out by the reaction of isatin, activated methylene reagents, and 4- hydroxycoumarin in aqueous medium. SBA-Pr-NH2 was found to be an efficient heterogeneous nanoporous solid basic catalyst (pore size of 6 nm) which can be easily handled and removed from the reaction mi...
[ 21 ] - Modification of mesoporous silica SBA-15 with different organic molecules to gain chemical sensors: a review
The recognition of the biologically and environmentally important ions is of great interest in the field of chemical sensors in recent years. The fluorescent sensors as a powerful optical analytical technique for the detection of low level of various analytes such as anions and metal cations have been progressively developed due to the simplicity, cost effective, and selectivity for monitoring ...
[ 22 ] - Efficient Synthesis and Antimicrobial Evaluation of Pyrazolopyranopyrimidines in the Presence of SBA-Pr-SO3H as a Nanoporous Acid Catalyst
A simple, efficient, and environmentally friendly method has been developed for the synthesis of a series of tricyclic fused pyrazolopyranopyrimidines via a one-pot three-component reaction of barbituric acids, aromatic aldehydes, and 3-methyl-5-pyrazolone in the presence of SBA-Pr-SO3H. SBA-15 mesoporous silica material functionalized with propyl sulfonic acid groups was used as a heterogeneou...
[ 23 ] - Synthesis of Some Spiro Indeno[1,2-b]pyrido[2,3-d]Pyrimidine-5,3′- Indolines as New Urease Inhibitors
New series of spiroindeno[1,2-b]pyrido[2,3-d]pyrimidine-5,3′-indolines as new urease inhibitors were synthesized by the catalytic procedure in high yield and short reaction time. In this method, biacidic carbon was prepared as a novel heterogeneous acid and was subsequently used as an efficient catalyst in this synthesis. The inhibitory activities of synthesized compounds were tested against Ja...
[ 24 ] - Green Synthesis and Urease Inhibitory Activity of Spiro-pyrimidinethiones/spiro-Pyrimidinones-barbituric Acid Derivatives
Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H) with pore size 6 nm as an efficient heterogeneous nanoporous solid acid catalyst exhibited good catalytic activity in the Biginelli-like reaction in the synthesis of spiroheterobicyclic rings with good yield and good recyclability. Spiro-pyrimidinethiones/spiro-pyrimidinones-barbituric acid derivatives were synthesized in a simple and efficient ...
[ 25 ] - تهیه و شناسایی نانومتخلخل V-SBA-16و کاربرد آن به عنوان کاتالیست در فرایند اکسایش مستقیم بنزن به فنل
در این پژوهش، کاتالیست V-SBA-16 با استفاده از ماده نانومتخلخل SBA-16 به عنوان بستر و کمپلکس وانادیم طی فرایند بازروانی تهیه شد. کاتالیست تهیه شده با استفاده از فناوری های جذب و واجذب نیتروژن،پراش پرتو ایکس، پرتو سنجی فرابنفش ـ مرئی و میکروسکوپ الکترونی عبوری مورد شناسایی قرار گرفت. نتیجه های آنالیزها نشان داد که ساختار منظم نانومتخلخل بستر در طی فرایند تهیه کاتالیست حفظ شده و دچار فروپاش...
[ 26 ] - Synthesis of tetra-substituted phenanthroimidazole derivatives using SBA-Pr-SO3H
A one pot four-component reaction of 9,10-phenanthraquinone, aromatic aldehyde, aniline, and ammonium acetate was designed for the preparation of tetrasubstituted imidazoles (phenanthro[9,10-d]imidazole) derivatives in the presence of SBA-Pr-SO3H as a mesoporous solid acid catalyst. Phenanthro[9,10-d]imidazole derivatives were produced by the use of this technique in short reaction times and go...
[ 27 ] - استخراج نقره از محلول عکاسی با استفاده از جاذب نانومتخلخل SBA-15 عاملدار شده با تریآمینفلوئورن
در این پژوهش، سیلیکای نانومتخلخل SBA-15 با 3-[2-(2-آمینواتیل آمینو) اتیلآمینو] پروپیلتریمتوکسیسیلان اصلاح شد. سپس، با پیوند مشتقی از فلوئورن بر سطح داخلی آن، سیلیکای نانومتخلخل SBA-15 عاملدار شده با مشتق تریآمین فلوئورن تهیه شد. برای شناسایی نمونهها روشهای پراش پرتو ایکس (XRD)، جذب - واجذب گاز نیتروژن و طیفسنجی FTIR بهکار گرفته شدند. سپس، قابلیت این ترکیب در استخراج کاتیونهای نقره ...
[ 28 ] - Synthesis of the biologically active henna based benzochromene derivatives using ionic liquid functionalized SBA-15 as a nanoreactor
SBA-15 was prepared and then functionalized with N-methyl-N’-propyltrimethoxysilyl imidazolium chloride as ionic liquid moiety. The ionic liquid functionalized SBA-15 (SBA-IL) was characterized by different analytical techniques including FT-IR, N2 adsorption-desorption, TGA and SEM image. According to the obtained results it was found that the organic groups were g...
[ 29 ] - Preparation and characterization of ionic liquid functionalized SBA-15 and its application in the synthesis of 2,3-dihydroquinazolinones
N-Methyl-Nʹ-propyltrimethoxysillylimidazolium chloride was prepared as ionic liquid (IL) containing silylating agent and then used for modification of the internal surface of SBA-15 to gain a heterogeneous ionic liquid catalyst. Subsequently, the obtained SBA-IL was characterized using various techniques, including SEM and TEM images, FT-IR, X-ray diffraction, TGA/DTA and BET ...
[ 30 ] - One-pot synthesis of tetrahydropyrimido[4,5-b]quinoline derivatives using sulfonic acid functionalized SBA-15 and their antimicrobial activities
A Simple and efficient method for synthesis of tetrahydropyrimido[4,5-b]quinoline derivatives via three component reaction of aromatic aldehydes, dimedone and 6-amino uracil derivatives using a catalytic amount of sulfonic acid functionalized nanoporous silica (SBA-15-Pr-SO3H) is described. The advantages of this method are easy and clean work-up, high yield, mild reaction c...
[ 31 ] - Fast one-pot synthesis of 1,8-dioxo-decahydroacridine derivatives using sulfonic acid functionalized LUS-1 and the study on their antimicrobial activities
Mesoporous silica LUS-1 (Laval University Silica) was successfully functionalized by propyl sulfonic acid and was used as a recyclable catalyst for the synthesis of acridine-1,8-diones via a pseudo four component reaction of aromatic aldehydes, dimedone and ammonium acetate (or anilines). The excellent yields, short reaction time, simple work-up procedure, and environmentally friendly condition...
[ 32 ] - Application of SBA-Pr-SO3H as a solid acid nanoreactor in the Biginelli reaction
Sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) with a pore size of 6 nm catalyzed three component coupling of aromatic aldehydes, urea and ethyl acetoacetate to afford the corresponding dihydropyrimidinones under solvent free condition. This new protocol for Biginelli reaction has important advantages such as green synthesis, short reaction time, easy isolation and high yields of ...
[ 33 ] - Green synthesis of bis(indolyl)methanes in water using sulfonic acid functionalized silica (SiO2-Pr-SO3H)
Bis(indolyl)methanes are important group of bioactive metabolites of terrestrial and marine regions. They were synthesized by different methods. Herein, a clean, one-pot synthesis of bis(indolyl)methane derivatives by cyclo-condensation reaction of indole and various aldehydes using Sulfonic acid functionalized silica (SiO2-Pr-SO3H) in aqueous media is reported. The advantages of this new metho...
[ 34 ] - A Green Multicomponent One-pot Synthesis of 9, 10-Diaryl-7H-benzo[d,e]imidazo[2,1-a]isoquinolin-7-one Derivatives using Nanoporous Base Silica (SBA-Pr-NH2) as Catalyst
Organic-inorganic hybrid mesoporous materials such as amino functionalized silica (SBA-Pr-NH2) have received considerable attention due to their basic catalytic applications and adsorption functions. In this work, we investigated the efficient role of SBA-Pr-NH2 as a heterogeneous nano catalyst in the synthesis of 9,10-diaryl-7H-benzo[d,e]imidazo[2,1-a]isoquinolin-7-one derivatives. Application...
[ 35 ] - A green method for the synthesis of indeno[1,2-b]pyridines using Fe3O4@SiO2@PrSO3H as a nanomagnetic catalyst
The acidic agent (SO3H) was stabilized on the silica coated Fe3O4 magnetic nanoparticles to produce Fe3O4@SiO2@Pr-SO3H, as a heterogeneous acidic catalyst, was designed, and then fully studied and characterized by FT-IR, XRD, TGA, DTA, TEM, and SEM analysis. Subsequently, the catalytic activity of Fe3O4...
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