Reza Fazaeli
Department of Chemical Engineering, Faculty of Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran.
[ 1 ] - Experimental design study of RB 255 photocatalytic degradation under visible light using synthetic Ag/TiO2 nanoparticles: Optimization of experimental conditions
In the present study, silver-doped TiO2 (Ag/TiO2) nanoparticles were prepared by various Ag doping (wt%) and a combination of sol-gel and ultrasound irradiation. Ag/TiO2 nanoparticles were characterized by energy-dispersive X-ray analysis (EDX), scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. Based on the Taguchi method, photocatalytic...
[ 2 ] - DFT study of dimers of dimethyl sulfoxide in gas phase
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interactions between dimethyl sulfoxide (DMSO) dimers. The structures obtained have been analyzed with the Atoms in Molecules (AIMs) and Natural Bond Orbital (NBO) methodologies. Four minima were located on the potential energy surface of the dimers. Three types of interactions are observed, CH•••O, CH•••...
[ 3 ] - The effect of cationic surfactant on the structure, morphology and optical band gap of ferrites synthesized by a microwave sol–gel auto-combustion method
Cu and Ni ferrites as the semiconductor materials were synthesized by a microwave sol-gel auto-combustion method. Two cationic surfactants, sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB), were applied and the influence of surfactants on the properties of the Cu and Ni ferrite particles was studied. The samples were characterized by X-ray powder diffraction (XRD) pattern,...
[ 4 ] - مطالعه اثر فلز طلا به‌عنوان ارتقادهنده برای افزایش ویژگی فوتوکاتالیستی نیم‌رسانای مس (I) اکسید
در این پژوهش، نانوذرات مس (I) اکسید با استفاده از مس استات به‌عنوان پیش ساز به روش فوق اشباع سنتز شد. به‌منظور افزایش ویژگی فوتوکاتالیستی Au بر روی نانوذرات Cu2O به روش تلقیح مرطوب بارگذاری شد و با استفاده از روش‌های پراش پرتو XRD) X)، میکروسکوپ الکترونی روبشی (SEM) و تجزیه عنصری به روش EDX مورد مشخصه یابی قرار گرفت. تخریب فوتوکاتالیستی رنگ آزویی Direct Red 264 با نانوذرات Cu2O و Au بارگذاری شد...
[ 5 ] - سنتز نانوذرات فریت مس به روش سل ژل خود احتراقی و بررسی ایزوترم‌های جذبی در تخریب فوتوکاتالیستی ماده رنگزای قرمز مستقیم 264
نانو ذرات فریت مس به روش سل ژل احتراقی تهیه شدند و به وسیله دستگاه‌های XRD، SEM، FT-IR و UV-VIS مورد بررسی قرار گرفتند. بررسی الگوی XRD و طیف FT-IR، تشکیل فاز فریت اسپینل را تایید کردند. متوسط اندازه بلوری ذرات توسط رابطه شرر محاسبه شده و 77 نانومتر است. ریخت‌شناسی و اندازه نانو ذرات تهیه شده توسط میکروسکوپ الکترونی روبشی مشاهده شد. انرژی باند گپ ذرات توسط داده‌های DRS محاسبه شد. نانو ذرات فریت...
[ 6 ] - Experimental design study of RB 255 photocatalytic degradation under visible light using synthetic Ag/TiO2 nanoparticles: Optimization of experimental conditions
In the present study, silver-doped TiO2 (Ag/TiO2) nanoparticles were prepared by various Ag doping (wt%) and a combination of sol-gel and ultrasound irradiation. Ag/TiO2 nanoparticles were characterized by energy-dispersive X-ray analysis (EDX), scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. Based on the Taguchi method, photocatalytic...
[ 7 ] - Solvent influence on the interaction of cis-PtCl2(NH3)2 complex and graphene: A theoretical study
In this study the interaction of cis-PtCl2(NH3)2 complex and graphene were investigated with MPW1PW91method in gas and solvent phases. The solvent effect was examined by the self-consistent reaction fieldtheory (SCRF) based on Polarizable Continuum Model (PCM). The selected solvents were chloroform,chlorobenzene, bromoethane, dimethyldisulfide, and dichloroethane. The solvent ...
[ 8 ] - Adsorption Study of Reactive Violet 8 and Congo Red Dyes onto Aloe Vera Micropowder Impregnated with Cu Atoms as a Natural Modified Sorbent and Related Kinetics and Thermodynamics
In this research, at first ordinary Aloe Vera micropowder (OAMP) and its impregnated form (IAMP) as the natural sorbents were prepared and then characterized by several techniques such as Fourier transform spectrophotometry (FT-IR), Scanning electron microscopy (SEM), Elemental analysis (EA), Brunauer–Emmett–Teller and Barrett-Joyner-Halenda (BET/BJH) essay and X-ray powder diffraction (XRD). T...
[ 9 ] - Optimization and Modeling of Complete Removal of N-Compounds from Oil Cut Using Response Surface Methodology (RSM) by CuAlO2/ZSM-12&35 as a New Photocatalyst
In this study, immobilized CuAlO2 onto the ZSM-12&35 composite was prepared and used as a photocatalyst to remove N-containing oil pollutants (Carbazole) through advanced oxidation. In this method, acetone is used as a reaction solvent that can be partially converted to fuel oxygenates compounds (Octane enhancers) through an aldol condensation reaction. Photocatalyst characterization was perfor...
[ 10 ] - Nanophotocatalytic Desulfurization of Hydrophane 10 Base Oil of Tehran Refinery
In this research, Ni(8%)/TiO2/Zeolite NaX nanophotocatalyst was synthesized andevaluated as a desulfurizer catalyst from hydrophane 10 base oil. Various tests,including X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Analysis (EDXA), Transmission Electron Microscopy (TEM), AtomicForce Microscopy (AFM), and BET/BJH were used to evaluat...
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