M. Behzad

[ 1 ] - Low Temperature Hydrothermal Synthesis and Characterization and Optical Properties of Sr5Nb4O15 – Nb2O5 Nanocomposite

Sr5Nb4O15 – Nb2O5 nanocomposites were synthesized in 2 and 4 M KOH aqueous solutions, via a non-stoichiometric 1:2 Sr:Nb molar ratio hydrothermal method at 160°C for 48 h (S1 and S2, respectively). Sr(NO3)2 and Nb2O5 were used as raw materials. The synthesized nanomaterials were characterized by powder X-Ray diffraction (PXRD) technique. It was found that Sr5Nb4O15 has been crystallized in hexa...

[ 2 ] - Alfa- Bismuth(III)oxide catalyzed Biginelli reactions using experimentally designed optimized condition

α-Bi2O3 was synthesized via a hydrothermal method at 180 °C for 12 h in 1 (S1) and 2 (S2) M KOH aqueous solutions, using Bi(NO3)3•5H2O as raw material. The synthesized material was characterized by X-ray powder diffraction (XRPD) technique. The XRPD results indicated that by using 1M KOH aqueous solution, α-Bi2O3 was obtained with small fractions of β-Bi2O3, while 2M KOH solution resulted in pu...

[ 3 ] - Bismuth Pyromangenate: Hydrothermal and Solid State Synthesis, Characterization and Optical Properties

Bi2Mn2O7 nano-powders were synthesized via a stoichiometric 1:1 Bi:Mn molar ratio hydrothermal method at 180 °C for 48 h in a 1M NaOH aqueous solution; and solid state method, using Bi(NO3)3.5H2O and MnO2 as raw materials. The synthesized materials were characterized by powder X-ray diffraction (PXRD) technique. Also, the rietveld analysis was done in FullProf in profile matching mode. It was f...

[ 4 ] - Low temperature hydrothermal synthesis, evaluation of band gap energies and catalytic performance for Biginelli reactions of Sr2-xAxNb2O7+δ (A=Eu3+ and Nd3+) (x = 0.01 and 0.05) nanomaterials

Nano powders Eu3+ and Nd3+ - doped Sr2Nb2O7 were prepared by a low temperature hydrothermalmethod at 120 ºC for 48 h followed by annealing at 400 ᵒC for 3 h among Sr(NO3)2and Nb2O5, Eu2O3 and Nd2O3 raw materials at stoichiometric 1:1 Sr:Nb molar ratio. Characterizationof the synthesized materials was performed by X-ray powder diffraction (XRPD)technique. FullProf program employing profile match...

[ 5 ] - Experimentally designed optimized conditions for catalytic performance of nanostructured RuO2 in Biginelli reaction

Nanostructured RuO2 powders were synthesized via a hydrothermal method at 180 °C for 12 h using 1 and 2 M NaOH aqueous solutions. The structure of the obtained nanomaterials was investigated by powder X-ray diffraction (PXRD) technique. The morphology the obtained materials were studied by field emission scanning electron microscope (FESEM). The technique showed that with changing the reaction ...

[ 6 ] - Manganese Antimonate: Facile solid state synthesis, characterization and its application for Biginelli reactions

Nanostructured Mn2Sb2O7 powders were synthesized via stoichiometric1:1 Mn:Sb molar ratio solid state reaction at different reactions temperatures for 8 h using MnSO4.H2O and Sb2O3 as raw materials. The synthesized materials were characterized by powder X-ray diffraction (PXRD) technique. Structural analyses were performed by the FullProf program employing profile matching with constant scale fa...

[ 7 ] - سنتز نانوذرات CeO2 با استفاده از روش هیدروترمال و محلول: مطالعه مقایسه ای

[ 8 ] - سنتز، شناسایی، و بررسی تاثیر الکترونگاتیوی بر ویژگی‌های الکتروشیمیایی و کاتالیزوری یک سری از کمپلکس‌های باز شیف جدید اکسووانادیم

در کار حاضر سنتز، شناسایی و بررسی ویژگی‌های الکتروشیمیایی و کاتالیزوری کمپلکس‌های جدید اکسووانادیم (IV) با دو لیگاند باز شیف چهاردندانه از نوع N2O2 سالوفنی بررسی شده است. لیگاندهای چهاردندانه‌ای حاصل از تراکم 4- نیترو- و 4- متیل- 1،2- فنیلن دی‌آمین با سالیسیل آلدهید بودند. توانایی کاتالیزوری این کمپلکس‌ها در فرایند اپوکسایش سیکلواکتن توسط ترشیو- بوتیل- هیدروژن پراکسید (TBHP)مطالعه شد و اثرات ن...

[ 9 ] - حذف رنگ‌های راکتیو از پساب‌های نساجی با استفاده از کربن فعال حاصل از پسماندهای دانه کنجد روکش‌شده با پلی‌وینیل‌الکل

در این پژوهش، خواص جذبی کربن فعال تهیه شده از پسماند حاصل از دانه‌های روغن‌کشی شده کنجد که با پلی‌وینیل‌الکل روکش شده‌ بودند، برای حذف رنگ‌های راکتیو قرمز 198 و آبی 19 از پساب صنایع نساجی مطالعه شد. مجموعه فرایند برای تعیین تعدادی از فاکتورهای مؤثر در ظرفیت جذبی پلی‌وینیل‌الکل مورد استفاده قرار گرفت و تأثیر pH، مقدار جا...

[ 10 ] - Structural, magnetic and electrical properties of pure and Dy-doped Fe2O3 nanostructures synthesized using chemical thermal decomposition technique

Pure (S1) and Dy3+-doped α-Fe2O3 (S2 and S3) nanoparticles were prepared by a combustion synthesis method at 700 ºC for 8 h using Fe(acac)3 (Tris(acetylacetonato)Iron(III)) as raw material. Characterizations of the prepared powders were carried out by powder X-ray diffraction (PXRD). Structural analysis was performed b...

[ 11 ] - Structural, magnetic and dielectric properties of pure and Dy-doped Co3O4 nanostructures for the electrochemical evolution of oxygen in alkaline media

In this study, spinel-type cobalt oxide (Co3O4) and Co3-xDyxO4 (x = 0.04 and 0.05 molar ratio) nanoparticles were synthesized via combustion method at 700 °C. Crystallite nature, phase purity and thermal analysis of the prepared compounds were investigated by PXRD, FT-IR and TGA techniques. Structural analyses were performed by the FullProf program employing profile matching with constant scale...

[ 12 ] - کانمیت تهیه شده از خاکستر پوسته برنج به عنوان یک کاتالیزور بازی موثر، ارزان قیمت و قابل بازیافت برای تولید بیودیزل

در این پژوهش، کانمیت از خاکستر پوسته برنج تهیه شده، و به عنوان یک کاتالیزور ناهمگن بازی برای تولید بیودیزل از روغن آفتابگردان استفاده شد. خصوصیات کاتالیزور با استفاده از تکنیک‌های PXRD، FESEM و FT-IR شناسایی گردید. پارامترهای موثر در واکنش ترانس استریفیکاسیون برای تولید بیودیزل از قبیل مقدار کاتالیزور، نسبت مولی متانول به روغن، زمان واکنش و دمای واکنش بهینه شد. تحت شرایط بهینه (% 5 وزنی کاتالیز...

[ 13 ] - Low Temperature Hydrothermal Synthesis and Characterization and Optical Properties of Sr5Nb4O15 – Nb2O5 Nanocomposite

Sr5Nb4O15 – Nb2O5 nanocomposites were synthesized in 2 and 4 M KOH aqueous solutions, via a non-stoichiometric 1:2 Sr:Nb molar ratio hydrothermal method at 160°C for 48 h (S1 and S2, respectively). Sr(NO3)2 and Nb2O5 were used as raw materials. The synthesized nanomaterials were characterized by powder X-Ray diffraction (PXRD) technique. It was found that Sr5Nb4O15 has been crystallized in hexa...

[ 14 ] - Structural, magnetic and electrical properties of pure and Dy-doped Fe2O3 nanostructures synthesized using chemical thermal decomposition technique

Pure (S1) and Dy3+-doped α-Fe2O3 (S2 and S3) nanoparticles were prepared by a combustion synthesis method at 700 ºC for 8 h using Fe(acac)3 (Tris(acetylacetonato)Iron(III)) as raw material. Characterizations of the prepared powders were carried out by powder X-ray diffraction (PXRD). Structural analysis was performed b...

[ 15 ] - Hydrothermal synthesis, characterization and catalytic performance of La3+ and Sm3+ - doped Bi2Mn2O7 nanocatalysts for Biginelli reactions

La3+ and Sm3+ - doped Bi2Mn2O7 nanocatalysts were synthesized in 1 M NaOH aqueous solution, via a stoichiometric 1:1 Bi:Mn molar ratio hydrothermal method at 180 °C for 48 h. Bi(NO3)3, MnO2, La(NO3)3 and Sm2O3 were used as raw materials. The synthesized nanomaterials were characterized by powder X-ray diffraction (PXRD) technique. Both of the La3+ and Sm3+ - doped Bi2Mn2O7 nanomaterials were cr...

[ 16 ] - Bioactive Salen-type Schiff Base Transition Metal Complexes as Possible Anticancer Agents

Although metal-based anticancer drugs have been recognized as the most effective agents over the organic compounds, non-selectivity and high toxic effects have limited their applications in a way that only three Pt-analogues have progressed into clinical use. These problems have spurred chemists to develop different strategies based on alternative targets. This work focuses on predicting potenc...

[ 17 ] - Bioactive Salen-type Schiff Base Transition Metal Complexes as Possible Anticancer Agents

Although metal-based anticancer drugs have been recognized as the most effective agents over the organic compounds, non-selectivity and high toxic effects have limited their applications in a way that only three Pt-analogues have progressed into clinical use. These problems have spurred chemists to develop different strategies based on alternative targets. This work focuses on predicting potenc...

[ 18 ] - Kanemite: an easily prepared and highly efficient catalyst for biodiesel production optimized by response surface methodology

Kanemite was readily prepared and used as solid base catalyst for transesterification of sunflower oil to fatty acid methyl ester (FAME). The catalyst was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N2 adsorption-desorption and field emission scanning electron microscopy (FESEM) techniques. Central Composite Design (CCD) coupled with Response Surfac...