One-Pot Reduction of Aromatic Carboxylic Acid to Alcohol by SiO2@FeSO4 Nano Composite at Solvent-free Condition

One-pot synthesis of Benzimidazole derivatives under microwave Irradiation and solvent-free condition

A simple, fast, efficient and environmentally friendly method for synthesis of benzimidazole and its 2-alkyl, aryl and heteroaryl substituted derivatives was developed using zeolite HY. Two component cyclolcondensation of 1,2-phenylenediamine (o-phenylenediamine) and commercially available carboxylic acids catalyzed by zeolite HY without any solvent, under microwave irradiation led to formation...

CuCl2 Catalyzed Solvent-free One Pot Synthesis of Dihydropyrimidinones

Synthesis of Some Biginelli-type Products: Nano Alumina Sulfonic acid (NASA) Catalyzed under Solvent-free Condition

Biginelli-type reaction was developed by means of a three-component condensation of analdehyde, ethyl acetoacetate, urea or thiourea and nano alumina sulfonic acid (Al2O3-SO3H)(NASA) as catalyzed. It is carried out under different conditions. In all conditions, the desiredproducts are obtained in high yields after relatively short reaction times. Nevertheless, thereactions proceeded faster and ...

Nano-Silica Phosphoric Acid: An Efficient Catalyst for One-Pot Synthesis of Tetrahydrobenzo[a]xanthenes-11-one Under Solvent- Free or Sonication Conditions

Two simple protocols for the synthesis of tetrahydrobenzo[a]xanthenes-11-ones using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

One-pot Efficient Oximation-Beckmann Rearrangement of Ketones Catalyzed by Fe3O4 Under Solvent-free Conditions

Fe3O4 nanoparticles were employment as an efficient and magnetically separable Nano catalyst for the synthesis of amides via one-pot Beckmann rearrangement of ketones under solvent-free conditions. Various secondary amides were synthesized by this method in moderate to good yields. The catalyst showed high thermal stability and was recovered and reused at least five times without any considerab...

One-Pot solvent-free synthesis of Highly Substituted Imidazoles catalyzed by zeolite

A series of tri- and tetra- substituted imidazoles were synthesized from benzyl, aldehyde and ammonium acetate in the presence of zeolite as an ecofriendly reusable catalyst under microwave irradiation in the absence of solvent. The yields are high to excellent and the use of microwave irradiation reduces reaction times to few minute.