Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes
نویسندگان
چکیده مقاله:
Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions.
منابع مشابه
mn-metal organic framework as heterogenous catalyst for oxidation of alkanes and alkenes
manganese metal-organic framework (mn-mof) containing mn2+ ions, benzenetricarboxylic acid (btc) and n,n-dimethylformamid (dmf) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, e...
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چکیده ندارد.
Mn(II)-Schiff base complex immobilized onto MCM-41 matrix as a heterogeneous catalyst for epoxidation of alkenes
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عنوان ژورنال
دوره 27 شماره 1
صفحات 31- 37
تاریخ انتشار 2016-01-01
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