Joel T. Mague
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA
[ 1 ] - Surface-grafted Europium and Erbium Complexes of the 12-Tungstosilicate Heteropolyoxometalate: A Synthetic and Structural Investigations
The hydrothermal synthesis of two new inorganic-organic hybrid materials in which PDA (PDA = 1,10-phenanthroline-2,9-dicarboxylate) is connected to a well-defined Keggin-type polyoxometalate anion (POM) and a Ln(III) cation (POM = [SiW12O40]4−; Ln = Eu3+ (1), Er3+ (2)), are reported. These hybrids are characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. Single-c...
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