Farzaneh Fadaei
CCC-IPSB, École Polytechnique Fédérale de Lausanne, Le Cubotron, Dorigny, CH-1015 Lausanne, Switzerland
[ 1 ] - The Flight of the Monarch: [Cu(L)(CH3CN)(PPh3)]ClO4 (L = 2,5-Diphenyl-3,4-bis(2-pyridyl) Cyclopenta-2,4-dien-1-one)
The mononuclear complex [Cu(L)(CH3CN)(PPh3)]ClO4, (1), (L= 2,5-diphenyl-3,4-bis(2-pyridyl)cyclopenta-2,4-dien-1-one), has been synthesized and investigated by elemental analysis, IR, 1H NMR, UV-Vis spectroscopic methods and X-ray diffraction. The complex crystallizes in the non-centrosymmetric space group P212121 in accord with the asymmetric (atropisomer) Cu centre. Its coordination polyhedron...
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