Haif Alshammari
Inorganic Chemistry Laboratory, University of Bayreuth, D-95440 Bayreuth, Germany
[ 1 ] - Dissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...
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