Gholam Abbas Parsafar
Faculty of Chemistry, Sharif University of Technology, P.O. Box 11365-9516 Tehran, I.R. IRAN
[ 1 ] - Density and Temperature Dependencies of Liquid Surface Tension
In this paper the density and temperature dependencies of surface tension are investigated. Using the Lennard-Jones (12,6), as an effective pair interaction potential, a linear expression is derived for isotherms of g /r2 versus r2 for some normal and ChloroFluoroCarbons (CFCs)</...
[ 2 ] - Extension of the Dense System Equation of State to Electrolyte Solutions
In this work we have applied the Dense System Equation of State (DSEOS) to electrolyte solutions. We have found that this equation of state can predict the density of electrolyte solutions very accurately. It has been tested for different electrolytes solutions at different temperatures and compositions. A hypothetical binary model has been applied to find the dependencies of parameters of ...
[ 3 ] - Viscosity Calculation of Supercritical Gases Based on the Rainwater-Friend Theory and the Modified Enskog Theory
A new correlation function for the calculation of viscosity for five typical supercritical gases is presented using the rainwater-Friend and modified Enskog theory. It is shown that by using accurate value for the thermal pressure and co-volume in the modified Enskog theory, this correlation function is suitable for calculation of the viscosity of supercritical gases, without any density an...
[ 4 ] - Pressure Dependence of Liquid Vapor Pressure: An Improved Gibbs Prediction
A new model for the vapor phase of a pressurized liquid called "the cluster model: which is originally introduced in this work, along with an accurate equation of state for the liquid phase called the LIR, is used to derive an accurate equation for the vapor pressure of liquid as a function of external pressure. The chemical Potential of both phase have been found to be in good agreement wi...
[ 5 ] - A New Tri-Parametrical Law of Corresponding States for Subcritical Dense Fluids
This article introduces a new tri-parameter law of corresponding states from the known regularities, namely the LIR and Zeno line for dense fluids (when Tz=Tc). Two of these parameters are the Zeno line parameters and the third parameter (the fluid parameter), has been obtained from the LIR, this parameter is solely dependent upon the fluid characteristics. The third parameter ca...
[ 6 ] - A Study of Na/K Feldspar Solid Solution Using Statistical Mechanics
Thermal behavior of various solid feldspars are different, namely those of bivalent cations show no change in the distribution of Al and Si atoms, whereas feldspars of univalent cations become more disordered with raising temperature. In the latter case Al atoms migrate from the sites they occupe at low temperatures and interchange positions with the Si atoms. At high temperatures (but stil...
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