Mehdi Bakavoli
Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, P.O. Box 91775-1436, Mashhad, Iran.
[ 1 ] - Synthesis of 2,4,5-triaryl-1H-imidazoles using a potent, green and reusable nano catalyst (FHS/SiO2)
A simple, green and efficient method for synthesis of 2,4,5-trisubstituted imidazoles is described via three-component cyclocondensation of benzil or benzoin, aldehyde and ammonium acetate by using the nano SiO2-supported ferric hydrogen sulfate (FHS/SiO2), as a catalyst, under solvent-free conditions. The nano SiO2 support and catalyst were characterized by X-ray diffraction (XRD), transmissio...
[ 2 ] - A Synthetic Approach for Evaluation of Cytosinediazonium Susceptibility
Reaction of a nucleobase with nitrosonium ion leads to its diazotization. Due to the instability,the nucleobase-diazonium assumingly falls in dediazotization and successive ring openingreactions. The resulting intermediate of the ring opening reaction is able to covalently cross-linkthe opposite strands of DNA. To examine this assumption for cytosine, some 4-amino-5-cyanopyrimidines were synthe...
[ 3 ] - Efficient Solvent Free Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a]-xanthen-11-ones and 3H-Spiro[isobenzofuran-1,9'-xanthen]-3-one Derivatives Using Cobalt Hydrogensulfate as a Green, Heterogeneous and Reusable Catalyst
Cobalt hydrogensulfate is an efficient catalyst for the condensation of β-naphthol, aromatic aldehydes and 5,5-dimethyl-1,3-cyclohexanedione at 120 °C to afford 9,9-dimethyl-12-phenyl-8,10,11,12-tetrahydro-9-H-benzo[a]xanthen-11-one derivatives in high yields. Also, polycondensation reactions of phenols with phthalic anhydride were carried out in the presence of cobalt hydrogensu...
[ 4 ] - Synthesis of 2,4,5-triaryl-1H-imidazoles using a potent, green and reusable nano catalyst (FHS/SiO2)
A simple, green and efficient method for synthesis of 2,4,5-trisubstituted imidazoles is described via three-component cyclocondensation of benzil or benzoin, aldehyde and ammonium acetate by using the nano SiO2-supported ferric hydrogen sulfate (FHS/SiO2), as a catalyst, under solvent-free conditions. The nano SiO2 support and catalyst were characterized by X-ray diffraction (XRD), transmissio...
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