Mohammad Kazem Mohammadi
Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
[ 1 ] - One pot three-component synthesis of imidazole derivatives using NH3/NH4Cl
Imidazole is a planar, five membered heteroaromatic molecule with pyrrole type and pyridine type annular nitrogens. Several approaches are available of imidazoles from alpha halo ketones, aminonitrile, aldehyde ect. Reactivity of imidazole and benzimidazole is referred from sets of resonance structure in which the dipolar contributors have finite importance. Imidazoles among the principal grou...
[ 3 ] - TiO2 nanoparticles/melamine Tri sulfonic acid for biginelli syntheis under solvent-free conditions
TiO2 nanoparticles/melamine Tri sulfonic acid (MTSA) supported on silica gel as an efficient catalytic system for simple, one pot, solvent-free and environmentally benign process for synthesis of dihydropyrimidines via Biginelli reaction at 110 °C is described. It was found that the catalyst is reusable and exhibited remarkable activity. The catalyst can be easily separated and reused several t...
[ 4 ] - Microwave assisted synthesis of [4, 5-e] [1, 3, 4]thia- diazin-7-yl] hydrazine Derivatives
New pyrimido [4, 5-e] [1, 3, 4]thia- diazin-7-yl] hydrazines were synthesized via the cyclocondensation of alkyl-2-phenylhydrazinecarbodithioates as a binucleophile with 5-bromo-2,4-dichloro-6-methylpyrimidine as a bielectrophile , and replacement of C-7 chloro atom by hydrazine in ethanol as the solvent . This method has advantages over methods currently described in the literature for the con...
[ 5 ] - Adsorption Evaluation of Food and Industrial Dyes on Nano copper oxide
In This applicable research, investigating absorption of process ofErythrosine dye on Copper oxide Nano particles Adsorbent was studied. First, prepared dyeconcentrations of 6, 8 and 12 mg L-1 and then effects of parameters such as concentrations ofinitial dye, time and pH on dye absorption efficiency were investigated.The dyeconcentrations in different samples were measured via spectrophotomet...
[ 6 ] - Synthesis of thiadiazine-3,7-diamine derivatives
New 1,5-tetra alkyl methyl- phenyl-1H-pyrimido[4,5-e][1,3,4]thiadiazine-3,7-diamine were synthesized via the cyclocondensation of 2-(5-bromo-2-chloro-6-methylpyrimidin-4-yl)-2-methylhydrazine with phenylthioisothiocyanate and further replacement of chlorine atom on the seven number position of pyrimido[4, 5- e][1, 3, 4]thiadiazin by appropriate secondary amines in simple and efficient methods.
[ 7 ] - Microwave assisted oxidation coupling of thiols to symmetrical disulfides with tripropylammonium fluorochromate (VI) (TPAFC)
Tripropylammonium fluorochromate(VI) (TPAFC), is an efficient and new reagent, which isprepared easily and oxidizes thiols to the corresponding disulfides, quickly. The reactions areperformed cleanly and are controlled to stop at the disulfide stage, without over-oxidation andside products. Coupling of thiols to their corresponding disulfides, are studied in solution atroom temperature and in s...
Co-Authors