THE EFFECT OF CRYOLITE NA3ALF6 AND SODIUM FLUORIDE NAF ON THE CORROSION AND WETTING BY MOLTEN AL-SI ALLOY OF ANDALUSITE BASED REFRACTORIES

Authors

  • A. Arab Fatideh Material Science and Engineering Department University of Tabriz, Tabriz, Iran.
  • H. Safabinesh Material Science and Engineering Department University of Tabriz, Tabriz, Iran.
  • M. Navidirad Material Science and Engineering Department University of Tabriz, Tabriz, Iran.
Abstract:

In order to improve the corrosion resistance of aluminosilicate refractories by molten aluminum, alkaline fluoride NaF and cryolite Na3AlF6 powders were studied. Both physical and chemical properties are known to influence wetting and corrosion behavior. This paper devoted to determine the influence of alkaline fluoride and cryolite added to andalusite based castable on the reaction with aluminum alloys. These additives led to the in-situ formation of celsian phases within the refractory matrix that led to improved corrosion resistance at 1300°C. Phase analysis revealed that celsian formation suppressed the formation of mullite within refractories, thereby reducing Penetration

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Journal title

volume 11  issue 3

pages  75- 82

publication date 2014-09

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